Issue 28, 2022

Bis(di-tert-butylindenyl)tetrelocenes

Abstract

The synthesis and characterization of bis(di-tert-butylindenyl) germanium(II), tin(II) and lead(II) complexes are reported, which includes the first structurally authenticated example of a bis(indenyl)germanocene. The species were studied in detail in solution and in the solid, which includes single crystal X-ray diffraction and NMR spectroscopy, as well as Mössbauer spectroscopy of the tin compound.

Graphical abstract: Bis(di-tert-butylindenyl)tetrelocenes

Supplementary files

Article information

Article type
Paper
Submitted
23 2 2022
Accepted
08 4 2022
First published
14 4 2022
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2022,51, 10714-10720

Bis(di-tert-butylindenyl)tetrelocenes

L. H. Staub, J. Lambert, C. Müller, B. Morgenstern, M. Zimmer, J. Warken, A. Koldemir, T. Block, R. Pöttgen and A. Schäfer, Dalton Trans., 2022, 51, 10714 DOI: 10.1039/D2DT00582D

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