Issue 33, 2021

Solution-processing of semiconducting organic small molecules: what we have learnt from 5,11-bis(triethylsilylethynyl)anthradithiophene

Abstract

Organic semiconducting small molecules have attracted increasing interest over the last decades because of their versatile, tunable optoelectronic properties and, e.g., the ease they can be purified compared to polymeric systems. Hence, over the past few decades, a large number of small molecules, such as acenes and thiophenes, have been explored for use in semiconducting devices such as thin-film transistors. However, many of these materials can adopt various molecular arrangements, producing polymorphic structures. As a result, the same material can display vastly different optoelectronic properties. This can, in many cases, lead to a large spread of device performances. Hence, it is critical to establish knowledge- and characterization libraries towards relevant structure/processing/performance interrelations to further advance this interesting class of materials and to open new application platforms. Here, we discuss processing strategies and methodologies that allow the control and assessment of polymorph formation in semiconducting small molecules using 5,11-bis(triethylsilylethynyl)anthradithiophene (TES ADT) as a model material system. We revise how a window into the complex phase behavior of semiconducting small molecules can be obtained, how specific polymorphs can be induced, and how post-deposition treatments can be exploited. Moreover, we illustrate pathways towards patterned structures as needed to fully exploit the touted potential of this interesting class of semiconductors.

Graphical abstract: Solution-processing of semiconducting organic small molecules: what we have learnt from 5,11-bis(triethylsilylethynyl)anthradithiophene

Article information

Article type
Review Article
Submitted
28 3 2021
Accepted
03 6 2021
First published
04 6 2021

J. Mater. Chem. C, 2021,9, 10547-10556

Author version available

Solution-processing of semiconducting organic small molecules: what we have learnt from 5,11-bis(triethylsilylethynyl)anthradithiophene

L. Yu, G. Portale and N. Stingelin, J. Mater. Chem. C, 2021, 9, 10547 DOI: 10.1039/D1TC01418H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements