Issue 57, 2021

Hg3(Te3O8)(SO4): a new sulfate tellurite with a novel structure and large birefringence explored from d10 metal compounds

Abstract

Our exploration of novel inorganic solids with large birefringence in the d10 Metal–Te4+–SO42− system afforded four new sulfate tellurites, Ga2(TeO3)(SO4)(OH)2, In2(TeO3)2(SO4)(H2O), Zn4(Te3O7)2(SO4)2(H2O) and Hg3(Te3O8)(SO4). Notably, Hg3(Te3O8)(SO4) exhibits the largest birefringence at 532 nm (0.184) and 1064 nm (0.166) among the reported metal sulfate tellurites.

Graphical abstract: Hg3(Te3O8)(SO4): a new sulfate tellurite with a novel structure and large birefringence explored from d10 metal compounds

Supplementary files

Article information

Article type
Communication
Submitted
11 5 2021
Accepted
15 6 2021
First published
16 6 2021

Chem. Commun., 2021,57, 7039-7042

Hg3(Te3O8)(SO4): a new sulfate tellurite with a novel structure and large birefringence explored from d10 metal compounds

P. Li, C. Hu, Y. Gong, F. Kong and J. Mao, Chem. Commun., 2021, 57, 7039 DOI: 10.1039/D1CC02494A

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