Issue 9, 2020

Copper mediated C(sp2)–H amination and hydroxylation of phosphinamides

Abstract

Copper mediated C(sp2)–H amination and hydroxylation of arylphosphinic acid are accomplished by adopting phosphinamide as the directing group. This method is distinguished by its wide substrate scope and excellent functional group tolerance, thus allowing for the rapid preparation of organophosphorus compounds in organic synthesis.

Graphical abstract: Copper mediated C(sp2)–H amination and hydroxylation of phosphinamides

Supplementary files

Article information

Article type
Communication
Submitted
13 11 2019
Accepted
20 12 2019
First published
21 12 2019

Chem. Commun., 2020,56, 1444-1447

Copper mediated C(sp2)–H amination and hydroxylation of phosphinamides

S. Sun, M. Shang, H. Xu, T. Cheng, M. Li and H. Dai, Chem. Commun., 2020, 56, 1444 DOI: 10.1039/C9CC08879B

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