Issue 60, 2019

Switching the enantioselectivity of nanoporous host materials by light

Abstract

A chiral photoswitchable nanoporous material with remote-controllable enantioselective adsorption capacity is presented. This metal–organic framework possesses both homochiral D-camphoric acid and light-responsive azobenzene moieties. Although the structure at the chiral moieties is unaffected, the transcis-azobenzene-photoisomerization changes the pore environment and, thus, switches the enantioselective adsorption behavior of the homochiral MOF.

Graphical abstract: Switching the enantioselectivity of nanoporous host materials by light

Supplementary files

Article information

Article type
Communication
Submitted
12 4 2019
Accepted
08 5 2019
First published
08 5 2019
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2019,55, 8776-8779

Switching the enantioselectivity of nanoporous host materials by light

A. B. Kanj, J. Bürck, S. Grosjean, S. Bräse and L. Heinke, Chem. Commun., 2019, 55, 8776 DOI: 10.1039/C9CC02849H

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