Issue 33, 2018

Development of catalytic nitrogen fixation using transition metal–dinitrogen complexes under mild reaction conditions

Abstract

This paper describes our recent progress in catalytic nitrogen fixation using transition metal–dinitrogen complexes as catalysts. Our research group has recently developed novel reaction systems for the catalytic transformation of molecular dinitrogen into ammonia and hydrazine using molybdenum–, iron–, cobalt– and vanadium–dinitrogen complexes under mild reaction conditions. The new findings presented in this paper may provide a new approach to the development of economical nitrogen fixation to replace the energy-consuming Haber–Bosch process.

Graphical abstract: Development of catalytic nitrogen fixation using transition metal–dinitrogen complexes under mild reaction conditions

Article information

Article type
Perspective
Submitted
24 6 2018
Accepted
26 7 2018
First published
26 7 2018

Dalton Trans., 2018,47, 11290-11297

Author version available

Development of catalytic nitrogen fixation using transition metal–dinitrogen complexes under mild reaction conditions

Y. Nishibayashi, Dalton Trans., 2018, 47, 11290 DOI: 10.1039/C8DT02572J

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