Issue 30, 2016

Flow-dependent separation selectivity for organic molecules on metal–organic frameworks containing adsorbents

Abstract

A new flow-dependent separation selectivity (FDSS) effect was discovered in isocratic HPLC. Significant changes in chromatographic selectivity were achieved by simple variation of the mobile phase flow rate. The FDSS effect was observed for a core–shell stationary phase using silica particles as a core and a Zr-based metal–organic framework (UiO-66) as a shell.

Graphical abstract: Flow-dependent separation selectivity for organic molecules on metal–organic frameworks containing adsorbents

Supplementary files

Article information

Article type
Communication
Submitted
06 1 2016
Accepted
18 3 2016
First published
18 3 2016
This article is Open Access
Creative Commons BY license

Chem. Commun., 2016,52, 5301-5304

Flow-dependent separation selectivity for organic molecules on metal–organic frameworks containing adsorbents

A. Peristyy, P. N. Nesterenko, A. Das, D. M. D'Alessandro, E. F. Hilder and R. D. Arrua, Chem. Commun., 2016, 52, 5301 DOI: 10.1039/C6CC00111D

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