Issue 2, 2015

Platinum-decorated carbon nanotubes for hydrogen oxidation and proton reduction in solid acid electrochemical cells

Abstract

Pt-decorated carbon nanotubes (Pt-CNTs) were used to enhance proton reduction and hydrogen evolution in solid acid electrochemical cells based on the proton-conducting electrolyte CsH2PO4. The carbon nanotubes served as interconnects to the current collector and as a platform for interaction between the Pt and CsH2PO4, ensuring minimal catalyst isolation and a large number density of active sites. Particle size matching was achieved by using electrospray deposition to form sub-micron to nanometric CsH2PO4. A porous composite electrode was fabricated from electrospray deposition of a solution of Pt-CNTs and CsH2PO4. Using AC impedance spectroscopy and cyclic voltammetry, the total electrode overpotential corresponding to proton reduction and hydrogen oxidation of the most active electrodes containing just 0.014 mg cm−1 of Pt was found to be 0.1 V (or 0.05 V per electrode) at a current density of 42 mA cm−2 for a measurement temperature of 240 °C and a hydrogen-steam atmosphere. The zero bias electrode impedance was 1.2 Ω cm2, corresponding to a Pt utilization of 61 S mg−1, a 3-fold improvement over state-of-the-art electrodes with a 50× decrease in Pt loading.

Graphical abstract: Platinum-decorated carbon nanotubes for hydrogen oxidation and proton reduction in solid acid electrochemical cells

Supplementary files

Article information

Article type
Edge Article
Submitted
30 9 2014
Accepted
10 12 2014
First published
22 12 2014
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2015,6, 1570-1577

Author version available

Platinum-decorated carbon nanotubes for hydrogen oxidation and proton reduction in solid acid electrochemical cells

V. S. Thoi, R. E. Usiskin and S. M. Haile, Chem. Sci., 2015, 6, 1570 DOI: 10.1039/C4SC03003F

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