Issue 10, 2014

Mechanism of CO2 hydrogenation to formates by homogeneous Ru-PNP pincer catalyst: from a theoretical description to performance optimization

Abstract

The reaction mechanism of CO2 hydrogenation by pyridine-based Ru-PNP catalyst in the presence of DBU base promoter was studied by means of density functional theory calculations. Three alternative reaction channels promoted by the complexes potentially present under the reaction conditions, namely the dearomatized complex 2 and the products of cooperative CO2 (3) and H2 (4) addition, were analysed. It is shown that the bis-hydrido Ru-PNP complex 4 provides the unique lowest-energy reaction path involving a direct effectively barrierless hydrogenolysis of the polarized complex 5*. The reaction rate in this case is controlled by the CO2 activation by Ru–H that proceeds with a very low barrier of ca. 20 kJ mol−1. The catalytic reaction can be hampered by the formation of a stable formato-complex 5. In this case, the rate is controlled by the H2 insertion into the Ru–OCHO coordination bond, for which a barrier of 65 kJ mol−1 is predicted. The DFT calculations suggest that the preference for the particular route can be controlled by varying the partial pressure of H2 in the reaction mixture. Under H2-rich conditions, the former more facile catalytic path should be preferred. Dedicated kinetic experiments verify these theoretical predictions. The apparent activation energies measured at different H2/CO2 molar ratios are in a perfect agreement with the calculated values. Ru-PNP is a highly active CO2 hydrogenation catalyst allowing reaching turnover frequencies in the order of 106 h−1 at elevated temperatures. Moreover, a minor temperature dependency of the reaction rate attainable in excess H2 points to the possibility of efficient CO2 hydrogenation at near-ambient temperatures.

Graphical abstract: Mechanism of CO2 hydrogenation to formates by homogeneous Ru-PNP pincer catalyst: from a theoretical description to performance optimization

Supplementary files

Article information

Article type
Paper
Submitted
02 5 2014
Accepted
31 5 2014
First published
03 6 2014
This article is Open Access
Creative Commons BY license

Catal. Sci. Technol., 2014,4, 3474-3485

Mechanism of CO2 hydrogenation to formates by homogeneous Ru-PNP pincer catalyst: from a theoretical description to performance optimization

G. A. Filonenko, E. J. M. Hensen and E. A. Pidko, Catal. Sci. Technol., 2014, 4, 3474 DOI: 10.1039/C4CY00568F

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