Issue 84, 2014

Highly unusual interpenetration isomers of electroactive nickel bis(dithiolene) coordination frameworks

Abstract

The metalloligand [Ni(pedt)2] (pedt = 1-(pyridine-4-yl)ethylene-1,2-dithiolate) has been incorporated into two multi-dimensional structures for the first time. These coordination frameworks represent highly unusual interpenetration isomers and exhibit solid state redox and optical properties that reflect the electronically delocalised nature of the metalloligand.

Graphical abstract: Highly unusual interpenetration isomers of electroactive nickel bis(dithiolene) coordination frameworks

Supplementary files

Article information

Article type
Communication
Submitted
15 7 2014
Accepted
04 9 2014
First published
05 9 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 12772-12774

Highly unusual interpenetration isomers of electroactive nickel bis(dithiolene) coordination frameworks

T. B. Faust, P. M. Usov, D. M. D'Alessandro and C. J. Kepert, Chem. Commun., 2014, 50, 12772 DOI: 10.1039/C4CC05438E

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