Issue 65, 2014

Nucleobase-functionalized ABC triblock copolymers: self-assembly of supramolecular architectures

Abstract

RAFT polymerization afforded acrylic ABC triblock copolymers with self-complementary nucleobase-functionalized external blocks and a low-Tg soft central block. ABC triblock copolymers self-assembled into well-defined lamellar microphase-separated morphologies for potential applications as thermoplastic elastomers. Complementary hydrogen bonding within the hard phase facilitated self-assembly and enhanced mechanical performance.

Graphical abstract: Nucleobase-functionalized ABC triblock copolymers: self-assembly of supramolecular architectures

Supplementary files

Article information

Article type
Communication
Submitted
05 5 2014
Accepted
24 6 2014
First published
24 6 2014
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2014,50, 9145-9148

Author version available

Nucleobase-functionalized ABC triblock copolymers: self-assembly of supramolecular architectures

K. Zhang, G. B. Fahs, M. Aiba, R. B. Moore and T. E. Long, Chem. Commun., 2014, 50, 9145 DOI: 10.1039/C4CC03363A

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