Issue 49, 2013

Dioxygen mediated conversion of {Fe(NO)2}9 dinitrosyl iron complexes to Roussin's red esters

Abstract

The reactivity of a series of {Fe(NO)2}9 dinitrosyl iron complexes bearing thiolate ligands with molecular oxygen is reported. These reactions result in the formation of the corresponding Roussin's red esters along with thiolate oxidation. This reactivity is contrasted with that previously reported for {Fe(NO)2}10 complexes.

Graphical abstract: Dioxygen mediated conversion of {Fe(NO)2}9 dinitrosyl iron complexes to Roussin's red esters

Supplementary files

Article information

Article type
Communication
Submitted
15 1 2013
Accepted
24 4 2013
First published
25 4 2013

Chem. Commun., 2013,49, 5550-5552

Dioxygen mediated conversion of {Fe(NO)2}9 dinitrosyl iron complexes to Roussin's red esters

J. Fitzpatrick, H. Kalyvas, J. Shearer and E. Kim, Chem. Commun., 2013, 49, 5550 DOI: 10.1039/C3CC40352A

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