Issue 5, 2020

Photo-induced glycosylation using a diaryldisulfide as an organo-Lewis photoacid catalyst

Abstract

Photo-induced glycosylations of several acceptors with trichloroacetimidate donors using bis(2-naphthyl)disulfide as an organo-Lewis photoacid (LPA) catalyst proceeded effectively to give the corresponding glycosides in good to high yields. In addition, the ground and excited state absorption spectra of bis(2-naphthyl)disulfide with or without NEt3 suggested the Lewis acidity of bis(2-naphthyl)disulfide upon photo-irradiation.

Graphical abstract: Photo-induced glycosylation using a diaryldisulfide as an organo-Lewis photoacid catalyst

Supplementary files

Article information

Article type
Communication
Submitted
17 12 2019
Accepted
09 1 2020
First published
09 1 2020

Org. Biomol. Chem., 2020,18, 851-855

Photo-induced glycosylation using a diaryldisulfide as an organo-Lewis photoacid catalyst

N. Iibuchi, T. Eto, M. Aoyagi, R. Kurinami, H. Sakai, T. Hasobe, D. Takahashi and K. Toshima, Org. Biomol. Chem., 2020, 18, 851 DOI: 10.1039/C9OB02674F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements