Issue 29, 2016

Nanoscale electrodeposition of low-dimensional metal phases and clusters

Abstract

The present status of the problem of electrochemical formation of low-dimensional metal phases is reviewed. The progress in this field achieved in the last two decades is discussed on the basis of experimental results obtained in selected electrochemical systems with well defined single crystal substrates. The influence of crystallographic orientation and surface inhomogeneities of foreign substrates on the mechanism of formation and the atomic structure of two-dimensional (2D) metal phases in the underpotential deposition range is considered. The localized electrodeposition of metal nanoclusters on solid state surfaces applying the STM-tip as a nanoelectrode is demonstrated.

Graphical abstract: Nanoscale electrodeposition of low-dimensional metal phases and clusters

Article information

Article type
Minireview
Submitted
24 2 2016
Accepted
02 6 2016
First published
02 6 2016

Nanoscale, 2016,8, 13880-13892

Nanoscale electrodeposition of low-dimensional metal phases and clusters

G. Staikov, Nanoscale, 2016, 8, 13880 DOI: 10.1039/C6NR01547F

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