Solvent-free copper-catalyzed trisilylation of alkynes: a practical and atom-economical approach for accessing 1,1,1-trisilylalkanes

Jia Li and Shaozhong Ge

Green Chem., 2024, 26, 6032
DOI: 10.1039/D4GC00220B

Cobalt catalyzed chemoselective reduction of nitroarenes: hydrosilylation under thermal and photochemical reaction conditions

Surajit Panda, Amareshwar Nanda, Rakesh R. Behera, Rahul Ghosh and Bidraha Bagh

Chem. Commun., 2023, 59, 4527
DOI: 10.1039/D3CC00328K

1,10-Phenanthroline-based periodic mesoporous organosilica: from its synthesis to its application in the cobalt-catalyzed alkyne hydrosilylation

Xiao-Tao Lin, Yusuke Ishizaka, Yoshifumi Maegawa, Katsuhiko Takeuchi, Shinji Inagaki, Kazuhiro Matsumoto and Jun-Chul Choi

RSC Adv., 2023, 13, 7828
DOI: 10.1039/D2RA08272A

syn-Selective hydrosilylation and hydroboration of alkynes at room temperature catalyzed by a phosphine-free (NNN)Fe(ii) complex

Chandini Pradhan, Shivansh Dubey, Pragnya Paramita Samal, Sailaja Krishnamurty and Benudhar Punji

Catal. Sci. Technol., 2025, 15, 6716
DOI: 10.1039/D5CY00766F

Reductive deoxygenation of tertiary alcohols: a cobalt-catalyzed hydrosilylation approach

Swetarani Meher, Ratiraman Swain, Braja Kishore Marndi and Bidraha Bagh

Org. Biomol. Chem., 2026, 24, 473
DOI: 10.1039/D5OB01788B

Catalytic hydrosilylation using an immobilized Co-terpyridine complex activated by inorganic salts and its application in a flow reactor

Katsuaki Kobayashi, Norihisa Fukaya and Hiroshi Nakazawa

New J. Chem., 2023, 47, 11784
DOI: 10.1039/D3NJ01062G

Nascent developments in main group element-catalyzed hydrosilylation and dehydrogenative silylation of alkenes and alkynes

Arumugam Vignesh, Jiahao Liu, Zhe Wang, Yan Liu and Zhuofeng Ke

Org. Chem. Front., 2024, 11, 576
DOI: 10.1039/D3QO01777J

Regio- and stereoselective hydrosilylation of alkynes with alkoxysilanes for the synthesis of β-(Z) vinylsilanes catalyzed by a dirhodium(ii)/XantPhos complex

Liqun Yang, Wenkui Lu, Xiaoyu Wu, Yan Lu, Xiaomin Xie and Zhaoguo Zhang

Org. Chem. Front., 2024, 11, 448
DOI: 10.1039/D3QO01725G

Hydrosilylation of nitriles and tertiary amides using a zinc precursor

Ravi Kumar, Rohan Kumar Meher, Himadri Karmakar and Tarun K. Panda

Org. Biomol. Chem., 2024, 22, 3053
DOI: 10.1039/D4OB00161C

Research on inorganic activators of dibromo Co-terpyridine complex precatalyst for hydrosilylation

Katsuaki Kobayashi and Hiroshi Nakazawa

Dalton Trans., 2022, 51, 18685
DOI: 10.1039/D2DT03471A

General ppm-level Pd-catalysed asymmetric diarylalkyne hydrosilylation to access structurally diverse Si-stereogenic vinylsilanes

Heng Xu, Han-Xiao Yu, An-Jiu Wen, Fang-Ying Ling, Fei Ye, Li Li, Fuk Yee Kwong and Li-Wen Xu

Org. Chem. Front., 2025, 12, 106
DOI: 10.1039/D4QO01698J

The role of silicon in drug discovery: a review

Jenny-Lee Panayides, Darren Lyall Riley, Felix Hasenmaile and Willem A. L. van Otterlo

RSC Med. Chem., 2024, 15, 3286
DOI: 10.1039/D4MD00169A

An unusualtrans-hydrosilylation of prochiral 1,1-disubstituted cyclopropenes revealing the different nature of asymmetric palladium and rhodium catalysis

Han-Qi Zhou, Fang-Ying Ling, Xiao-Jun Fang, Hua-Jie Zhu, Li Li, Fei Ye, Zheng Xu and Li-Wen Xu

Org. Chem. Front., 2023, 10, 430
DOI: 10.1039/D2QO01688E

Access to Unsaturated Organogermanes via (De)Hydrosilylation Mediated by Cobalt Complexes

Konstancja Broniarz and Grzegorz Hreczycho

Org. Lett., 2023, 25, 6528
DOI: 10.1021/acs.orglett.3c02326

A theoretical study on the feasibility of 1,4-Copper migration in the Cu-catalyzed formal hydro(borylmethylsilyl)ation of internal alkynes

Song Liu, Wei Chen, Xinyu Long, Dianmin Zhang, Jingxu Chen, Zhou Zhu and Haobin Wei

Commun Chem, 2025, 9
DOI: 10.1038/s42004-025-01829-z

Selective Cobalt(II)–SNS Dithiolate Complex-Catalyzed Bifunctional Hydroboration of Aldehydes: Kinetics and Mechanistic Studies

Saeed Ataie, Samantha L. Dudra, Erin R. Johnson and R. Tom Baker

ACS Catal., 2023, 13, 10076
DOI: 10.1021/acscatal.3c02318

Cobalt-catalyzed synthesis of silyl ethers via cross-dehydrogenative coupling between alcohols and hydrosilanes

Ewelina Szafoni, Krzysztof Kuciński and Grzegorz Hreczycho

Green Chemistry Letters and Reviews, 2022, 15, 757
DOI: 10.1080/17518253.2022.2133554

Low‐coordinate cobalt(0) N‐heterocyclic carbene complexes as catalysts for hydrosilylation of alkynes

Wenli Bai, Jian Sun, Dongyang Wang, Sheng‐Di Bai and Liang Deng

Applied Organom Chemis, 2022, 36
DOI: 10.1002/aoc.6694

Cobalt‐Catalyzed Regiodivergent Double Hydrosilylation of Arylacetylenes

Zhaoyang Cheng, Minghua Li, Xu‐Yang Zhang, Yue Sun, Qing‐Lei Yu, Xing‐Hong Zhang and Zhan Lu

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202215029

Cobalt-Catalyzed Hydrosilylation Polymerization for the Synthesis of Linear Polycarbosilanes

Chunyu Chen, Ziwei Luo, Hao Zeng, Chaowei Hao, Ke-Fang Yang, Ze Li, Guo-Qiao Lai and Pinglu Zhang

Macromolecules, 2024
DOI: 10.1021/acs.macromol.4c01241

Accessing 3-Sulfonated Vinylsilanes via Sulfonylation of α-Bromoallylsilane Involving Photoinduced Radical Sulfur Dioxide Insertion

Jie Wang, Yang Luo, Shuo Gao, Xiaoqing Li and Xiangsheng Xu

J. Org. Chem., 2025, 90, 11716
DOI: 10.1021/acs.joc.5c01237

Progress in the catalytic applications of cobalt N–heterocyclic carbene complexes: Emphasis on their synthesis, structure and mechanism

Srinivasa Budagumpi, Rangappa S. Keri, D.H. Nagaraju, Zhoveta Yhobu, V. Monica, B.M. Geetha, Rashmi Dilip Kadu and Nupoor Neole

Molecular Catalysis, 2023, 535, 112850
DOI: 10.1016/j.mcat.2022.112850

Advances in catalysis using Xantphos-like ligands; simplicity goes a long way

Piet W.N.M. van Leeuwen, Israel Cano and Zoraida Freixa

Coordination Chemistry Reviews, 2025, 537, 216636
DOI: 10.1016/j.ccr.2025.216636

Mechanistic Insights on the β-(Z) alkyne hydrosilylation by a NHC-based Cp*Rh(III) catalyst: from catalyst design to an alternative model for H-Si activation

Isabel Poves-Ruiz, Beatriz Sánchez-Page, M. Victoria Jiménez, Miguel Gallegos, Julen Munarriz, Vincenzo Passarelli and Jesús J. Pérez-Torrente

Journal of Catalysis, 2026, 456, 116721
DOI: 10.1016/j.jcat.2026.116721

Hydrosilylation of Arynes with Silanes and Silicon‐Based Polymer

Ying Zhang, Zhenming Zang, Yuan Gao, Wenchang Li and Tingshun Zhu

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202401440

Bulky NHC–Cobalt Complex-Catalyzed Highly Markovnikov-Selective Hydrosilylation of Alkynes

Małgorzata Bołt and Patrycja Żak

Catalysts, 2023, 13, 510
DOI: 10.3390/catal13030510

Searching for highly active cobalt catalysts bearing Schiff base ligands for Markovnikov-selective hydrosilylation of alkynes with tertiary silanes

Maciej Skrodzki, Victor Ortega Garrido, Aurelio G. Csáky and Piotr Pawluć

Journal of Catalysis, 2022, 411, 116
DOI: 10.1016/j.jcat.2022.05.002

Copper-Catalyzed Formal Dihydrosilylation of Terminal Alkynes: A C(sp)–H Silylation-Hydrosilylation-Hydrogenation Sequence

Jia Li, Siqiang Fang and Shaozhong Ge

ACS Catal., 2024, 14, 7996
DOI: 10.1021/acscatal.4c01813

Hydrosilylation of Alkynes Catalyzed by an Iron(II) PCP Pincer Alkyl Complex

Heiko Schratzberger and Karl Kirchner

ChemCatChem, 2025, 17
DOI: 10.1002/cctc.202401398

Nickel-Catalyzed Mono- and Dihydrosilylation of Aliphatic Alkynes in Aqueous and Aerobic Conditions

Chanmi Lee, Ji Hwan Jeon, Soochan Lee, Wonyoung Choe, Jaesung Kwak, Sangwon Seo, Sung You Hong and Byunghyuck Jung

ACS Catal., 2024, 14, 5077
DOI: 10.1021/acscatal.4c00109

Effect of Substituted Terpyridine Ligands on Magnetic and CO2 Photoreduction Properties of High Spin Co(II)(tpy)Br2

Shriya Saha, Ibtesham Tarannum, Raúl Rojas-Luna, Jhuma Sannigrahi, Saurabh Kumar Singh, Souvik Roy and Raja Mitra

Inorg. Chem., 2026, 65, 1884
DOI: 10.1021/acs.inorgchem.5c04586

Ligand-controlled Cobalt-Catalyzed formation of Carbon–Boron bonds: Hydroboration vs C H/B–H dehydrocoupling

Dariusz Lewandowski, Tomasz Cytlak, Rhett Kempe and Grzegorz Hreczycho

Journal of Catalysis, 2022, 413, 728
DOI: 10.1016/j.jcat.2022.07.037

Redox Behavior of Cobalt–Phosphine Complexes vs Their Catalytic Activity in Organozinc Compound Formation: Background for Mechanistic Investigations

Mykyta O. Ivanytsya, Olena O. Pariiska, Andrey M. Mishura, Eduard B. Rusanov, Svitlana V. Shishkina, Alina O. Gorlova, Anton S. Lytvynenko, Sergey V. Ryabukhin, Dmitriy M. Volochnyuk and Sergey V. Kolotilov

Inorg. Chem., 2023, 62, 5906
DOI: 10.1021/acs.inorgchem.2c03816

Cobalt-Catalyzed Regio- and Stereoselective Hydrosilylation of Alk-2-ynes with Tertiary Silanes

Hongfang Li, Chengbo Yang, Dongyang Wang and Liang Deng

Organometallics, 2023, 42, 1693
DOI: 10.1021/acs.organomet.2c00563

Lithium Triethylborohydride (LiHBEt3)-Promoted Hydrosilylation of Allenes to Prepare (E)-Allylsilanes

Zhi-Kai Liu, Bin Wang, Yanzhi Liu, Zhen-Qiang Zhang and Zhuang-Ping Zhan

J. Org. Chem., 2023, 88, 12257
DOI: 10.1021/acs.joc.3c00848

Recent Progress of Platinum and Rhodium Catalysts in Hydrosilylation Reactions

Leila Mirghaffari, Seyedmohammad Hosseininezhad, Melika Seydi, Ali Ramazani, Hamideh Ahankar and Guoying Zhang

ChemistrySelect, 2025, 10
DOI: 10.1002/slct.202501079

Co‐catalyzed Selective syn‐Hydrosilylation of Internal Alkynes

Hanna Stachowiak‐Dłużyńska, Krzysztof Kuciński, Bożena Wyrzykiewicz, Rhett Kempe and Grzegorz Hreczycho

ChemCatChem, 2023, 15
DOI: 10.1002/cctc.202300592

Molybdenum-Catalyzed (E)-Selective Anti-Markovnikov Hydrosilylation of Alkynes

Feihua Ye, Zhaoyang Huang, Jiahao Li, Qiumin Wang, Lihuan Wu and Xiang Li

Molecules, 2024, 29, 5952
DOI: 10.3390/molecules29245952

Copper-Catalyzed Regio- and Enantioselective Hydrosilylation of Internal Alkynes for Synthesis of Si-Stereogenic Vinylsilanes

Xiao-Yan Zhu, Zi-Lu Wang, Jian-Lin Xu, Lei Xu, Xing Hu, Jun-Wei Zhang and Yun-He Xu

ACS Catal., 2025, 15, 15183
DOI: 10.1021/acscatal.5c04020

Cobalt‐Catalyzed Hydrosilylation across Carbon‐Carbon, Carbon‐Oxygen, and Carbon‐Nitrogen Multiple Bonds – A Comprehensive Review

Jisna Jose and Thomas V. Mathew

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202301626

Computational Insights into the Effect of Ligands and Transition-Metal Centers on the Mechanism and Regioselectivity of Hydrosilylation of Alkenes

Jian-Biao Liu, Hai-Yan Wang, Yan Wang and Xiao-Jun Liu

Inorg. Chem., 2024, 63, 23939
DOI: 10.1021/acs.inorgchem.4c04299

Manganese Phenoxyimine complexes: Structures, reactions, and water-assisted hydrosilylation of aldehydes

Kouki Matsubara, Kaichi Ikuta, Shoko Koga and Yuji Koga

Journal of Organometallic Chemistry, 2025, 1032, 123634
DOI: 10.1016/j.jorganchem.2025.123634

Catalytic asymmetric silicon-carbon bond-forming transformations based on Si-H functionalization

Li Li, Wei-Sheng Huang, Zheng Xu and Li-Wen Xu

Sci. China Chem., 2023, 66, 1654
DOI: 10.1007/s11426-022-1480-y

Homodinuclear Rare‐Earth Metal Complexes as Efficient Precatalysts for the Stereoselective Hydrosilylation of Inactivated Internal Diaryl Alkynes with (Aryl)(vinyl)silanes or Diphenylsilane

Xueqin Yan, Dongjing Hong, Zeming Huang, Zhuo Chai, Weigang Wang, Xiancui Zhu and Shaowu Wang

Chin. J. Chem., 2026, 44, 1181
DOI: 10.1002/cjoc.70475

Cobalt Nanoparticles Formed upon Reaction of Cp*Co(III) Metallacycles with Na[BHEt3] Show Catalytic Activity in the Hydrosilylation of Aryl Ketones, Aldehydes and Nitriles

Carmen Antuña‐Hörlein, Fule Wu, Christophe Deraedt, Corinne Bouillet and Jean‐Pierre Djukic

Eur J Inorg Chem, 2023, 26
DOI: 10.1002/ejic.202200563

The tale of alkyl- and acylcobalt carbonyls

Róbert Tuba, Róbert Kurdi and Gyula Pályi

Journal of Organometallic Chemistry, 2024, 1007, 123029
DOI: 10.1016/j.jorganchem.2024.123029

Cobalt‐Catalyzed Regiodivergent Double Hydrosilylation of Arylacetylenes

Zhaoyang Cheng, Minghua Li, Xu‐Yang Zhang, Yue Sun, Qing‐Lei Yu, Xing‐Hong Zhang and Zhan Lu

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202215029

Well-Defined Cobalt-Silyl Complexes and Their Role in Catalytic Carbonyl Hydrosilylation

Anthony L. Amaya, Hussah Alawisi, Hadi D. Arman and Zachary J. Tonzetich

Organometallics, 2023, 42, 2902
DOI: 10.1021/acs.organomet.3c00326