Issue 41, 2021
From the journal:

CrystEngComm

Mass spectrometry guided surface modification of a tellurate ion templated 36-nucleus silver alkynyl nanocluster†

Lin-Lin Hou, ORCID logo a   Hong-Jing Li,a   Dong-Nan Yu,a   Xun Cheng,a   Zi-Xuan Yao,a   Kuan-Guan Liu ORCID logo *a  and  Xiao-Wei Yan*b  

* Corresponding authors

a State Key Laboratory of High-efficiency Coal Utilization and Green Chemical Engineering, and Ningxia Key Laboratory of Photovoltaic Materials, Ningxia University, Yin-Chuan 750021, China
E-mail: liukuanguan@nxu.edu.cn

b College of Food and Bioengineering, Research Institute of Food Science and Engineering Technology, Hezhou University, Hezhou 542899, China
E-mail: yanxiaoweizb@163.com

Abstract

Under the guidance of the ESI-MS result for [TeO6@Ag36(C[triple bond, length as m-dash]CtBu)18(tfa)12] (1, tfa = trifluoroacetate), a new 36-nucleus silver-alkynyl cluster substituted by four pentafluorobenzoates, named as [TeO6@Ag36(C[triple bond, length as m-dash]CtBu)18(tfa)8(F5PhCO2)4] (2), has been fabricated. After shell ligand substitution, cluster 2 emits green yellow light in the solid state and shows a remarkable change in the near-infrared luminescence emission compared to cluster 1.

Graphical abstract: Mass spectrometry guided surface modification of a tellurate ion templated 36-nucleus silver alkynyl nanocluster

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D1CE01061A
Article type
Communication
Submitted
10 8 2021
Accepted
15 9 2021
First published
16 9 2021

CrystEngComm, 2021,23, 7202-7205

Permissions

Request permissions

Mass spectrometry guided surface modification of a tellurate ion templated 36-nucleus silver alkynyl nanocluster

L. Hou, H. Li, D. Yu, X. Cheng, Z. Yao, K. Liu and X. Yan, CrystEngComm, 2021, 23, 7202 DOI: 10.1039/D1CE01061A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements