Issue 11, 2016

Accurate structure determination of a borosilicate zeolite EMM-26 with two-dimensional 10 × 10 ring channels using rotation electron diffraction

Abstract

A new borosilicate zeolite |N2H36C16|[Si22B2O48]·H2O, denoted as EMM-26, has been synthesized by employing a linear dicationic organic structure directing agent 1,6-bis(N-methylpyrrolidinium)hexane (OSDA). EMM-26 has a novel zeolite framework and contains two-dimensional (2D) intersecting 10 × 10-ring channels. Its structure was solved from sub-micrometer sized crystals using rotation electron diffraction (RED) and refined against both the RED and synchrotron powder diffraction data. We have shown for the first time that RED data alone can be used to accurately determine zeolite structures. The OSDAs can be removed from the framework generating permanent pores. EMM-26 shows good CO2 uptake and CO2/CH4 selectivity.

Graphical abstract: Accurate structure determination of a borosilicate zeolite EMM-26 with two-dimensional 10 × 10 ring channels using rotation electron diffraction

Supplementary files

Article information

Article type
Research Article
Submitted
20 7 2016
Accepted
17 9 2016
First published
19 9 2016

Inorg. Chem. Front., 2016,3, 1444-1448

Accurate structure determination of a borosilicate zeolite EMM-26 with two-dimensional 10 × 10 ring channels using rotation electron diffraction

P. Guo, K. Strohmaier, H. Vroman, M. Afeworki, P. I. Ravikovitch, C. S. Paur, J. Sun, A. Burton and X. Zou, Inorg. Chem. Front., 2016, 3, 1444 DOI: 10.1039/C6QI00262E

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