Issue 45, 2013
From the journal:

CrystEngComm

Morphological diversity of Mn(iii) metalloporphyrin-based nano- and microsized CPAs assembled via kinetic and thermodynamic controls and their application in heterogeneous catalysis†

Kyung Yeon Lee,a   Young Sun Lee,a   Sundol Kim,a   Hoang Mai Ha,ac   Sang-Eun Bae,b   Seong Huh,b   Ho Gyeom Janga  and  Suk Joong Lee*a  

* Corresponding authors

a Department of Chemistry, Korea University, 5 Anam-dong, Sungbuk-gu, Seoul 136-701, Republic of Korea
E-mail: slee1@korea.ac.kr
Fax: +82 2 925 4284
Tel: +82 2 3290 3145

b Department Chemistry and Protein Research Center for Bio-Industry, Hankuk University of Foreign Studies, Yongin 449-791, Republic of Korea

c Institute of Chemistry, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam

Abstract

A series of narrowly dispersed nano- and microsized CPAs has been prepared from a (porphyrin)Mn(III) biscarboxylic acid and Co(OAc)2. The morphologies have been diversified from amorphous spheres to crystalline cubes by varying reaction periods. In addition, their heterogeneous catalytic olefin oxidations are successfully demonstrated.

Graphical abstract: Morphological diversity of Mn(iii) metalloporphyrin-based nano- and microsized CPAs assembled via kinetic and thermodynamic controls and their application in heterogeneous catalysis

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Article information

DOI
https://doi.org/10.1039/C3CE41072B
Article type
Communication
Submitted
09 6 2013
Accepted
24 8 2013
First published
29 8 2013

CrystEngComm, 2013,15, 9360-9363

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Morphological diversity of Mn(III) metalloporphyrin-based nano- and microsized CPAs assembled via kinetic and thermodynamic controls and their application in heterogeneous catalysis

K. Y. Lee, Y. S. Lee, S. Kim, H. M. Ha, S. Bae, S. Huh, H. G. Jang and S. J. Lee, CrystEngComm, 2013, 15, 9360 DOI: 10.1039/C3CE41072B

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