Issue 47, 2009
From the journal:

Chemical Communications

Stereoselective gold-catalyzed cycloaddition of functionalized ketoenynes: synthesis of (+)-orientalol F†‡

Eloísa Jiménez-Núñez,a   Kian Molawia  and  Antonio M. Echavarren*ab  

* Corresponding authors

a Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain
E-mail: aechavarren@iciq.es

b Departament de Química Analítica i Química Orgànica, Universitat Rovira i Virgili, C/Marcelli Domingo s/n, 43007 Tarragona, Spain

Abstract

A stereoselective gold-catalyzed [2 + 2 + 2] cycloaddition of ketoenynes substituted at the propargylic position with OR groups has been applied for the synthesis of (+)-orientalol F and pubinernoid B.

Graphical abstract: Stereoselective gold-catalyzed cycloaddition of functionalized ketoenynes: synthesis of (+)-orientalol F

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Article information

DOI
https://doi.org/10.1039/B920119J
Article type
Communication
Submitted
28 9 2009
Accepted
19 10 2009
First published
05 11 2009

Chem. Commun., 2009, 7327-7329

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Stereoselective gold-catalyzed cycloaddition of functionalized ketoenynes: synthesis of (+)-orientalol F

E. Jiménez-Núñez, K. Molawi and A. M. Echavarren, Chem. Commun., 2009, 7327 DOI: 10.1039/B920119J

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