Issue 52, 2024
From the journal:

Chemical Communications

A π-extended β-diketiminate ligand via a templated Scholl approach†

Lars Killian,a   Martin Lutz ORCID logo b  and  Arnaud Thevenon ORCID logo *a  

* Corresponding authors

a Organic Chemistry and Catalysis, Institute for Sustainable and Circular Chemistry, Faculty of Science, Utrecht University, Universiteitsweg 99, Utrecht, The Netherlands
E-mail: a.a.thevenon-kozub@uu.nl

b Structural Biochemistry, Bijvoet Centre for Biomolecular Research, Faculty of Science, Utrecht University, Universiteitsweg 99, Utrecht, The Netherlands

Abstract

We report a templated Scholl oxidation strategy for the preparation of the first β-diketiminate (BDI) ligands embedded within a 24-electron π-system backbone. The resulting benzo[f,g]tetracene BDI ligand was coordinated to a zinc centre and electrochemical studies showed the redox active nature of the ligand.

Graphical abstract: A π-extended β-diketiminate ligand via a templated Scholl approach

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Article information

DOI
https://doi.org/10.1039/D4CC01627K
Article type
Communication
Submitted
08 4 2024
Accepted
05 6 2024
First published
06 6 2024
This article is Open Access
Creative Commons BY license

Chem. Commun., 2024,60, 6663-6666

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A π-extended β-diketiminate ligand via a templated Scholl approach

L. Killian, M. Lutz and A. Thevenon, Chem. Commun., 2024, 60, 6663 DOI: 10.1039/D4CC01627K

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