Arylazopyrazole as a photo-switch for controllable self-assembly of pillar[6]arene-based supramolecular amphiphiles

Yishu Yu; Xiaotian Qu; Junran Li; Feihe Huang; Jie Yang

doi:10.1039/D3CC05018A

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Arylazopyrazole as a photo-switch for controllable self-assembly of pillar[6]arene-based supramolecular amphiphiles†

Yishu Yu,^a Xiaotian Qu,^a Junran Li,^a Feihe Huang

*^bc and Jie Yang

*^a

Author affiliations

* Corresponding authors

^a College of Science, Nanjing Forestry University, Nanjing 210037, P. R. China
E-mail: jieyang@njfu.edu.cn

^b Stoddart Institute of Molecular Science, Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. China
E-mail: fhuang@zju.edu.cn

^c Zhejiang-Israel Joint Laboratory of Self-Assembling Functional Materials, ZJU-Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou, China

Abstract

A photo-responsive host–guest molecular recognition between a cationic pillar[6]arene host and an arylazopyrazole derived guest was established. Based on this novel recognition motif, a photo-controllable supra-amphiphile was constructed. The spontaneous aggregation can be reversibly controlled by irradiation with UV (365 nm) and green light (520 nm), leading to a switch between spherical nanoparticles and vesicle-like aggregates.

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Article information

DOI: https://doi.org/10.1039/D3CC05018A
Article type: Communication
Submitted: 12 10 2023
Accepted: 07 11 2023
First published: 08 11 2023

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Chem. Commun., 2023,59, 14265-14268

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Arylazopyrazole as a photo-switch for controllable self-assembly of pillar[6]arene-based supramolecular amphiphiles

Y. Yu, X. Qu, J. Li, F. Huang and J. Yang, Chem. Commun., 2023, 59, 14265 DOI: 10.1039/D3CC05018A

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Chemical Communications

Arylazopyrazole as a photo-switch for controllable self-assembly of pillar[6]arene-based supramolecular amphiphiles†

Abstract

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Arylazopyrazole as a photo-switch for controllable self-assembly of pillar[6]arene-based supramolecular amphiphiles

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