Issue 15, 2022

A novel copper metal–organic framework catalyst for the highly efficient conversion of CO2 with propargylic amines

Abstract

The rapid increase in atmospheric carbon dioxide has resulted in the greenhouse effect. Hence, carbon dioxide capture and further fixation into valuable chemical products are particularly important for reducing atmospheric carbon dioxide concentrations. In this direction, a novel copper-based metal three-dimensional framework, Cu-TSP, was assembled from tripod ligands containing thiourea groups; this heterogeneous material can efficiently catalyze the reaction of propargylic amines and carbon dioxide to synthesize 2-oxazolidinones, and the recyclability and high conversion rates demonstrate the broad potential applications of this designed material as a π-activated catalyst in the chemical industry.

Graphical abstract: A novel copper metal–organic framework catalyst for the highly efficient conversion of CO2 with propargylic amines

Supplementary files

Article information

Article type
Research Article
Submitted
30 3 2022
Accepted
05 6 2022
First published
06 6 2022

Inorg. Chem. Front., 2022,9, 3839-3844

A novel copper metal–organic framework catalyst for the highly efficient conversion of CO2 with propargylic amines

X. Xu, Z. Li, H. Huang, X. Jing and C. Duan, Inorg. Chem. Front., 2022, 9, 3839 DOI: 10.1039/D2QI00678B

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