Issue 15, 2022

Surface chemistry of metal–organic polyhedra

Abstract

Metal–organic polyhedra (MOPs) are discrete, intrinsically-porous architectures that operate at the molecular regime and, owing to peripheral reactive sites, exhibit rich surface chemistry. Researchers have recently exploited this reactivity through post-synthetic modification (PSM) to generate specialised molecular platforms that may overcome certain limitations of extended porous materials. Indeed, the combination of modular solubility, orthogonal reactive sites, and accessible cavities yields a highly versatile molecular platform for solution to solid-state applications. In this feature article, we discuss representative examples of the PSM chemistry of MOPs, from proof-of-concept studies to practical applications, and highlight future directions for the MOP field.

Graphical abstract: Surface chemistry of metal–organic polyhedra

Article information

Article type
Feature Article
Submitted
14 12 2021
Accepted
25 1 2022
First published
25 1 2022
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2022,58, 2443-2454

Surface chemistry of metal–organic polyhedra

J. Albalad, L. Hernández-López, A. Carné-Sánchez and D. Maspoch, Chem. Commun., 2022, 58, 2443 DOI: 10.1039/D1CC07034G

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