Solvent-regulated biomorphs from the intense π,π-mediated assemblies of tetracenequinone fused porphyrin

Chen Chen; Dan Li; Guanyue Cao; Zhonghe Qin; Yi Xu; Xiujun Liu; Qizhao Li; Yongshu Xie; Chengjie Li

doi:10.1039/D1CE01173A

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Solvent-regulated biomorphs from the intense π,π-mediated assemblies of tetracenequinone fused porphyrin†‡

Chen Chen,^a Dan Li,^a Guanyue Cao,^a Zhonghe Qin,^b Yi Xu,^b Xiujun Liu,*^a Qizhao Li,^a Yongshu Xie^a and Chengjie Li

*^a

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* Corresponding authors

^a Key Laboratory for Advanced Materials and Institute of Fine Chemicals, Shanghai Key Laboratory of Functional Materials Chemistry, School of Chemistry & Molecular Engineering, East China University of Science & Technology, Shanghai, China
E-mail: liuxiujun@ecust.edu.cn, chengjie.li@ecust.edu.cn

^b Shanghai World Foreign Language Academy, Shanghai, China

Abstract

Tetracenequinone fused porphyrin Ni4TQ has been synthesized and the long tetracenequinone units at the vertices of porphyrin exhibit an intense π,π-interaction, which can be regulated by solvents to furnish different shapes of crystals or various uniform flower-shaped biomorphs.

This article is part of the themed collection: Supramolecular & Polymorphism

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DOI: https://doi.org/10.1039/D1CE01173A
Article type: Communication
Submitted: 31 8 2021
Accepted: 01 10 2021
First published: 01 10 2021

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CrystEngComm, 2021,23, 7565-7569

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Solvent-regulated biomorphs from the intense π,π-mediated assemblies of tetracenequinone fused porphyrin

C. Chen, D. Li, G. Cao, Z. Qin, Y. Xu, X. Liu, Q. Li, Y. Xie and C. Li, CrystEngComm, 2021, 23, 7565 DOI: 10.1039/D1CE01173A

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CrystEngComm

Solvent-regulated biomorphs from the intense π,π-mediated assemblies of tetracenequinone fused porphyrin†‡

Abstract

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Solvent-regulated biomorphs from the intense π,π-mediated assemblies of tetracenequinone fused porphyrin

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