Issue 34, 2021
From the journal:

CrystEngComm

Two isomeric zeolite-like metal–organic frameworks with mechanically responsive luminescence emission and gas adsorption properties†

Shuang Peng,‡a   Yan-Jie Qi,‡a   Xin-Hao Li,b   Cai Sun, ORCID logo a   Ling-Yun Li, ORCID logo b   Xin-Xiong Li, ORCID logo *a   Shou-Tian Zheng ORCID logo a  and  Qichun Zhang ORCID logo *cd  

* Corresponding authors

a State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
E-mail: lxx@fzu.edu.cn

b Key Laboratory of Eco-materials Advanced Technology, College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian 350108, China

c School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore, Singapore
E-mail: qczhang@ntu.edu.sg

d Center of Super-Diamond and Advanced Films (COSDAF), City University of Hong Kong, Hong Kong, SAR 999077, P. R. China

Abstract

Two isomeric zeolite-like metal–organic frameworks with the formula of [(CH3)2NH2][Cd(TPO)]·xsolvent were successfully prepared and characterized. Both frameworks are constructed from tetrahedral TPO3− nodes and tetrahedrally connected Cd2+ nodes, representing rare examples of zeolite-like MOFs with an isomeric characteristic. Moreover, one of the frameworks shows mechanically responsive luminescence emission after the crystals are ground for different times. Additionally, it has permanent porosity, and can selectively adsorb CO2 over N2.

Graphical abstract: Two isomeric zeolite-like metal–organic frameworks with mechanically responsive luminescence emission and gas adsorption properties

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D1CE00464F
Article type
Communication
Submitted
07 4 2021
Accepted
12 5 2021
First published
13 5 2021

CrystEngComm, 2021,23, 5753-5757

Permissions

Request permissions

Two isomeric zeolite-like metal–organic frameworks with mechanically responsive luminescence emission and gas adsorption properties

S. Peng, Y. Qi, X. Li, C. Sun, L. Li, X. Li, S. Zheng and Q. Zhang, CrystEngComm, 2021, 23, 5753 DOI: 10.1039/D1CE00464F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements