Switching the enantioselectivity of nanoporous host materials by light

Anemar Bruno Kanj; Jochen Bürck; Sylvain Grosjean; Stefan Bräse; Lars Heinke

doi:10.1039/C9CC02849H

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Switching the enantioselectivity of nanoporous host materials by light†

Anemar Bruno Kanj,

^a Jochen Bürck,

^b Sylvain Grosjean,

^c Stefan Bräse^cde and Lars Heinke

*^a

Author affiliations

* Corresponding authors

^a Karlsruhe Institute of Technology (KIT), Institute of Functional Interfaces (IFG), 76344 Eggenstein-Leopoldshafen, Germany
E-mail: Lars.Heinke@kit.edu

^b KIT, Institute of Biological Interfaces (IBG-2), 76344 Eggenstein-Leopoldshafen, Germany

^c KIT, Institute of Biological Interfaces 3 – Soft Matter Lab (IBG-3), 76344 Eggenstein-Leopoldshafen, Germany

^d KIT, Institute of Toxicology and Genetics (ITG), 76344 Eggenstein-Leopoldshafen, Germany

^e KIT, Institute of Organic Chemistry (IOC), 76131 Karlsruhe, Germany

Abstract

A chiral photoswitchable nanoporous material with remote-controllable enantioselective adsorption capacity is presented. This metal–organic framework possesses both homochiral D-camphoric acid and light-responsive azobenzene moieties. Although the structure at the chiral moieties is unaffected, the trans–cis-azobenzene-photoisomerization changes the pore environment and, thus, switches the enantioselective adsorption behavior of the homochiral MOF.

This article is part of the themed collection: 2019 Emerging Investigators

Download options Please wait...

Supplementary files

Supplementary information PDF (881K)

Article information

DOI: https://doi.org/10.1039/C9CC02849H
Article type: Communication
Submitted: 12 4 2019
Accepted: 08 5 2019
First published: 08 5 2019
This article is Open Access

Download Citation

Chem. Commun., 2019,55, 8776-8779

Permissions

Request permissions

Switching the enantioselectivity of nanoporous host materials by light

A. B. Kanj, J. Bürck, S. Grosjean, S. Bräse and L. Heinke, Chem. Commun., 2019, 55, 8776 DOI: 10.1039/C9CC02849H

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications

Switching the enantioselectivity of nanoporous host materials by light†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Switching the enantioselectivity of nanoporous host materials by light

Social activity

Search articles by author

Spotlight

Advertisements