Issue 14, 2018
From the journal:

Journal of Materials Chemistry A

A solvent-switched in situ confinement approach for immobilizing highly-active ultrafine palladium nanoparticles: boosting catalytic hydrogen evolution†

Qi-Long Zhu, ORCID logo a   Fu-Zhan Song,a   Qiu-Ju Wang,a   Nobuko Tsumori,c   Yuichiro Himeda,d   Tom Autreye  and  Qiang Xu ORCID logo *ab  

* Corresponding authors

a Research Institute of Electrochemical Energy, National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563-8577, Japan
E-mail: q.xu@aist.go.jp

b AIST-Kyoto University Chemical Energy Materials Open Innovation Laboratory (ChEM-OIL), Yoshida Sakyo-ku, Kyoto, Japan

c Toyama National College of Technology, 13, Hongo-machi, Toyama 939-8630, Japan

d Research Institute of Energy Frontier, AIST, Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan

e Pacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, Washington 99352, USA

Abstract

A facile and effective solvent-switched in situ confinement approach (SSISCA) has been developed to immobilize ultrafine and clean Pd NPs of ∼1.75 nm into a nanoporous carbon support. The Pd NPs in situ confined within the carbon nanopores possess high catalytic activity and selectivity for hydrogen evolution from formic acid with a record-high TOF of 9110 h−1 at 60 °C.

Graphical abstract: A solvent-switched in situ confinement approach for immobilizing highly-active ultrafine palladium nanoparticles: boosting catalytic hydrogen evolution

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Article information

DOI
https://doi.org/10.1039/C8TA01093E
Article type
Communication
Submitted
01 2 2018
Accepted
08 3 2018
First published
08 3 2018

J. Mater. Chem. A, 2018,6, 5544-5549

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A solvent-switched in situ confinement approach for immobilizing highly-active ultrafine palladium nanoparticles: boosting catalytic hydrogen evolution

Q. Zhu, F. Song, Q. Wang, N. Tsumori, Y. Himeda, T. Autrey and Q. Xu, J. Mater. Chem. A, 2018, 6, 5544 DOI: 10.1039/C8TA01093E

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