Synthesis and properties of heterobimetallic rhodium complexes featuring LiI, CuI or ZnII as a Lewis acidic metalloligand

Patrick Steinhoff; Ralf Steinbock; Anna Friedrich; Benjamin G. Schieweck; Christopher Cremer; Khai-Nghi Truong; Michael E. Tauchert

doi:10.1039/C8DT01267A

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Synthesis and properties of heterobimetallic rhodium complexes featuring Li^I, Cu^I or Zn^II as a Lewis acidic metalloligand†

Patrick Steinhoff,^a Ralf Steinbock,^a Anna Friedrich,^a Benjamin G. Schieweck,^a Christopher Cremer,

^a Khai-Nghi Truong

^a and Michael E. Tauchert

*^a

Author affiliations

* Corresponding authors

^a Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1A, D-52074 Aachen, Germany
E-mail: Michael.Tauchert@ac.rwth-aachen.de

Abstract

A series of [(PMP)Rh(CO)Cl]ⁿ⁺ complexes was synthesised and the impact of the metalloligands Cu^I, Li^I and Zn^II on the CO stretching band was analysed.

This article is part of the themed collection: New Talent: Europe

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Article information

DOI: https://doi.org/10.1039/C8DT01267A
Article type: Communication
Submitted: 31 3 2018
Accepted: 05 7 2018
First published: 13 7 2018

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Dalton Trans., 2018,47, 10439-10442

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Synthesis and properties of heterobimetallic rhodium complexes featuring Li^I, Cu^I or Zn^II as a Lewis acidic metalloligand

P. Steinhoff, R. Steinbock, A. Friedrich, B. G. Schieweck, C. Cremer, K. Truong and M. E. Tauchert, Dalton Trans., 2018, 47, 10439 DOI: 10.1039/C8DT01267A

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