Issue 30, 2016
From the journal:

Chemical Communications

Flow-dependent separation selectivity for organic molecules on metal–organic frameworks containing adsorbents†

Anton Peristyy,a   Pavel N. Nesterenko,a   Anita Das,b   Deanna M. D'Alessandro,b   Emily F. Hildera  and  R. Dario Arrua*a  

* Corresponding authors

a Australian Centre for Research on Separation Science, University of Tasmania, Private Bag 75, Hobart, TAS 7001, Australia
E-mail: Dario.Arrua@utas.edu.au, Dario.Arrua@unisa.edu.au

b School of Chemistry F11, University of Sydney, NSW 2006, Australia

Abstract

A new flow-dependent separation selectivity (FDSS) effect was discovered in isocratic HPLC. Significant changes in chromatographic selectivity were achieved by simple variation of the mobile phase flow rate. The FDSS effect was observed for a core–shell stationary phase using silica particles as a core and a Zr-based metal–organic framework (UiO-66) as a shell.

Graphical abstract: Flow-dependent separation selectivity for organic molecules on metal–organic frameworks containing adsorbents

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Article information

DOI
https://doi.org/10.1039/C6CC00111D
Article type
Communication
Submitted
06 1 2016
Accepted
18 3 2016
First published
18 3 2016
This article is Open Access
Creative Commons BY license

Chem. Commun., 2016,52, 5301-5304

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Flow-dependent separation selectivity for organic molecules on metal–organic frameworks containing adsorbents

A. Peristyy, P. N. Nesterenko, A. Das, D. M. D'Alessandro, E. F. Hilder and R. D. Arrua, Chem. Commun., 2016, 52, 5301 DOI: 10.1039/C6CC00111D

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