Structural alteration of the metal–organic pyrogallol[4]arene nano-capsule motif by incorporation of large metal centres

Ping Jin; Harshita Kumari; Stuart Kennedy; Charles L. Barnes; Simon J. Teat; Scott J. Dalgarno; Jerry L. Atwood

doi:10.1039/C4CC00202D

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Structural alteration of the metal–organic pyrogallol[4]arene nano-capsule motif by incorporation of large metal centres†

Ping Jin,^a Harshita Kumari,^a Stuart Kennedy,^a Charles L. Barnes,^a Simon J. Teat,^b Scott J. Dalgarno^c and Jerry L. Atwood*^a

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* Corresponding authors

^a Department of Chemistry, University of Missouri, 601 S. College Avenue, Columbia, MO 65211, USA
E-mail: AtwoodJ@missouri.edu
Fax: +1 573 882 2754
Tel: +1 573 882 8374

^b Advanced Light Source, Berkeley Lab, 1 Cyclotron Rd., MS6R2100, Berkeley, CA 94720, USA

^c Institute of Chemical Sciences, Heriot-Watt University, Riccarton, Edinburgh, UK

Abstract

Addition of cadmium(II) nitrate to gallium-coordinated metal–organic C-alkylpyrogallol[4]arene nano-capsules affords a variation of the near spherical hexamer motif, structural changes in which are induced by the markedly different nature of the secondary incorporated metal.

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DOI: https://doi.org/10.1039/C4CC00202D
Article type: Communication
Submitted: 09 1 2014
Accepted: 24 2 2014
First published: 24 3 2014

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Chem. Commun., 2014,50, 4508-4510

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Structural alteration of the metal–organic pyrogallol[4]arene nano-capsule motif by incorporation of large metal centres

P. Jin, H. Kumari, S. Kennedy, C. L. Barnes, S. J. Teat, S. J. Dalgarno and J. L. Atwood, Chem. Commun., 2014, 50, 4508 DOI: 10.1039/C4CC00202D

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Chemical Communications

Structural alteration of the metal–organic pyrogallol[4]arene nano-capsule motif by incorporation of large metal centres†

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Structural alteration of the metal–organic pyrogallol[4]arene nano-capsule motif by incorporation of large metal centres

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