Issue 75, 2012
From the journal:

Chemical Communications

Functional group effects on metal–organic framework topology†‡

Phuong V. Dau,a   Kristine K. Tanabea  and  Seth M. Cohen*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA, USA 92093
E-mail: scohen@ucsd.edu

Abstract

Functionalization of the ligand 1,3,5-tris(4-carboxyphenyl)benzene (H3BTB) has been realized with methoxy (H3BTB–[OMe]3) and hydroxy (H3BTB–[OH]3) groups. Combining H3BTB–[OMe]3 and Zn(II) results in the formation of the first isostructural, functionalized analogue of MOF-177 (MOF-177–OMe), while the combination of H3BTB–[OH]3 and Zn(II) generates a rare, interpenetrated pcu-e framework.

Graphical abstract: Functional group effects on metal–organic framework topology

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Article information

DOI
https://doi.org/10.1039/C2CC34938H
Article type
Communication
Submitted
11 7 2012
Accepted
07 8 2012
First published
08 8 2012

Chem. Commun., 2012,48, 9370-9372

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Functional group effects on metal–organic framework topology

P. V. Dau, K. K. Tanabe and S. M. Cohen, Chem. Commun., 2012, 48, 9370 DOI: 10.1039/C2CC34938H

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