Issue 10, 2011
From the journal:

New Journal of Chemistry

A meta-xylenediamidemacrocycle containing rotaxane anion host system constructed by a new synthetic clipping methodology†‡

Nicholas H. Evans,a   Christopher J. Serpella  and  Paul D. Beer*a  

* Corresponding authors

a Department of Chemistry, Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, UK
E-mail: paul.beer@chem.ox.ac.uk

Abstract

A novel rotaxane containing a meta-xylenediamide macrocycle is prepared by a new clipping methodology. Upon anion metathesis to the non-coordinating hexafluorophosphate salt, the rotaxane host system was shown to bind chloride and bromide anions more strongly than the basic oxoanions dihydrogen phosphate and acetate in the competitive solvent system 1 : 1 CDCl3 : CD3OD.

Graphical abstract: A meta-xylenediamide macrocycle containing rotaxane anion host system constructed by a new synthetic clipping methodology

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Article information

DOI
https://doi.org/10.1039/C1NJ20109C
Article type
Paper
Submitted
11 2 2011
Accepted
25 3 2011
First published
03 5 2011

New J. Chem., 2011,35, 2047-2053

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A meta-xylenediamide macrocycle containing rotaxane anion host system constructed by a new synthetic clipping methodology

N. H. Evans, C. J. Serpell and P. D. Beer, New J. Chem., 2011, 35, 2047 DOI: 10.1039/C1NJ20109C

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