Issue 2, 2010
From the journal:

Chemical Communications

Chiral bifunctional phase transfer catalysts for asymmetric fluorination of β-keto esters†‡

Xisheng Wang,a   Quan Lan,a   Seiji Shirakawaa  and  Keiji Maruoka*a  

* Corresponding authors

a Laboratory of Synthetic Organic Chemistry and Special Laboratory of Organocatalytic Chemistry, Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto, Japan
E-mail: maruoka@kuchem.kyoto-u.ac.jp
Fax: +81-75-753-4041
Tel: +81-75-753-4041

Abstract

Chiral bifunctional phase transfer catalysts introducing bis(diarylhydroxymethyl) substituents at 3,3′-positions of the chiral binaphthyl core were successfully applied to asymmetric fluorination of cyclic β-keto esters with high enantioselectivities.

Graphical abstract: Chiral bifunctional phase transfer catalysts for asymmetric fluorination of β-keto esters

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Article information

DOI
https://doi.org/10.1039/B920099A
Article type
Communication
Submitted
29 9 2009
Accepted
13 11 2009
First published
27 11 2009

Chem. Commun., 2010,46, 321-323

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Chiral bifunctional phase transfer catalysts for asymmetric fluorination of β-keto esters

X. Wang, Q. Lan, S. Shirakawa and K. Maruoka, Chem. Commun., 2010, 46, 321 DOI: 10.1039/B920099A

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