Issue 32, 2009

A catalytic synthesis of selectively substituted biaryls through sequential intermolecular coupling involving arene and ketone C–H bond functionalization

Abstract

Selectively substituted biaryls containing a ketone unit are obtained under mild conditions in satisfactory yields by a simple reaction of ortho-substituted aryl iodides and ketones in the presence of palladium and norbornene as catalysts.

Graphical abstract: A catalytic synthesis of selectively substituted biaryls through sequential intermolecular coupling involving arene and ketone C–H bond functionalization

Supplementary files

Article information

Article type
Communication
Submitted
08 5 2009
Accepted
12 6 2009
First published
01 7 2009

Chem. Commun., 2009, 4892-4894

A catalytic synthesis of selectively substituted biaryls through sequential intermolecular coupling involving arene and ketone C–H bond functionalization

G. Maestri, N. Della Ca’ and M. Catellani, Chem. Commun., 2009, 4892 DOI: 10.1039/B909207B

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