Issue 30, 2022
From the journal:

Organic & Biomolecular Chemistry

Visible-light-mediated oxidative C–S bond cleavage of benzyl thiols through in situ activation strategy†

Boseok Honga  and  Anna Lee ORCID logo *b  

* Corresponding authors

a Department of Chemistry, Myongji University, Yongin 17058, Republic of Korea

b Department of Chemistry, Jeonbuk National University, Jeonju 54896, Republic of Korea
E-mail: annalee@jbnu.ac.kr

Abstract

A novel method for the oxidative C–S bond cleavage of benzyl thiols was developed. In situ-activated silver species enabled the controlled bond cleavage of benzyl thiols to afford aldehydes and ketones in the absence of a photocatalyst. The desired carbonyl compounds were obtained under mild reaction conditions via two different reaction pathways.

Graphical abstract: Visible-light-mediated oxidative C–S bond cleavage of benzyl thiols through in situ activation strategy

  • This article is part of the themed collection: New Talent
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Article information

DOI
https://doi.org/10.1039/D2OB00089J
Article type
Communication
Submitted
14 1 2022
Accepted
15 2 2022
First published
15 2 2022

Org. Biomol. Chem., 2022,20, 5938-5942

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Visible-light-mediated oxidative C–S bond cleavage of benzyl thiols through in situ activation strategy

B. Hong and A. Lee, Org. Biomol. Chem., 2022, 20, 5938 DOI: 10.1039/D2OB00089J

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