Steric control of sorting regimes in self-assembled cages†
Samuel E.
Walker, 
a
Thomas
Malcomson,
b
Martin J.
Paterson,
c
Kellie L.
Tuck
a
and
David R.
Turner
*a
a
Thomas
Malcomson,
b
Martin J.
Paterson,
c
Kellie L.
Tuck
a
and
David R.
Turner
*a
Abstract
Control of self-sorting regimes is achieved through adjustment of steric interactions in self-assembled coordination cages. The self-assembly regime of dynamic mixtures of heteroleptic cages is followed by HPLC to show that statistical or biased distributions can be selectively obtained, including isolation of a single heteroleptic species.
- This article is part of the themed collections: Host-Guest Chemistry and Chemical Communications HOT articles
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