Issue 83, 2012

Control of framework interpenetration for in situ modified hydroxyl functionalised IRMOFs

Abstract

By intimate control of reaction conditions, phase-pure crystalline porous metal–organic framework materials [Zn4O(L)3] with interpenetrated and non-interpenetrated structures can be synthesised. Under certain conditions, these reactions occur with concomitant deprotection of masked alcohols located on the organic links which yield accessible ‘metal-binding’ functional groups within the frameworks.

Graphical abstract: Control of framework interpenetration for in situ modified hydroxyl functionalised IRMOFs

Supplementary files

Article information

Article type
Communication
Submitted
01 8 2012
Accepted
31 8 2012
First published
31 8 2012

Chem. Commun., 2012,48, 10328-10330

Control of framework interpenetration for in situ modified hydroxyl functionalised IRMOFs

D. Rankine, A. Avellaneda, M. R. Hill, C. J. Doonan and C. J. Sumby, Chem. Commun., 2012, 48, 10328 DOI: 10.1039/C2CC35565E

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