Preparation of novel, moisture-stable, Lewis-acidic ionic liquids containing quaternary ammonium salts with functional side chains

Andrew P. Abbott; Glen Capper; David L. Davies; Helen L. Munro; Raymond K. Rasheed; Vasuki Tambyrajah

doi:10.1039/B106357J

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Preparation of novel, moisture-stable, Lewis-acidic ionic liquids containing quaternary ammonium salts with functional side chainsElectronic supplementary information (ESI) available: plot of conductivity vs. temperature for the ionic liquid formed from zinc chloride and choline chloride (2∶1). See http://www.rsc.org/suppdata/cc/b1/b106357j/

Andrew P. Abbott,^a Glen Capper,^a David L. Davies,*^a Helen L. Munro,^a Raymond K. Rasheed^a and Vasuki Tambyrajah^a

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* Corresponding authors

^a Department of Chemistry, University of Leicester, Leicester, UK
E-mail: dld3@le.ac.uk

Abstract

A range of novel, moisture-stable, Lewis-acidic ionic liquids has been prepared by mixing appropriate molar ratios of MCl₂ (M = Zn and/or Sn) and quaternary ammonium salts of formula [Me₃NC₂H₄Y]Cl (Y = OH, Cl, OC(O)Me, OC(O)Ph); the influence of substituent Y and metal M on the physical properties of the melts has been investigated.

This article is part of the themed collection: ChemComm 60th Anniversary Historic Papers from the United Kingdom

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Supplementary files

Plot of conductivity against temperature for the ionic liquid formed from zinc chloride and choline chloride (2:1) DOC (31K)

Article information

DOI: https://doi.org/10.1039/B106357J
Article type: Communication
Submitted: 17 7 2001
Accepted: 29 8 2001
First published: 19 9 2001

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Chem. Commun., 2001, 2010-2011

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Preparation of novel, moisture-stable, Lewis-acidic ionic liquids containing quaternary ammonium salts with functional side chains

A. P. Abbott, G. Capper, D. L. Davies, H. L. Munro, R. K. Rasheed and V. Tambyrajah, Chem. Commun., 2001, 2010 DOI: 10.1039/B106357J

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Preparation of novel, moisture-stable, Lewis-acidic ionic liquids containing quaternary ammonium salts with functional side chains

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