Themed collection Aggregation-Induced Emission

Aggregation-induced emission in synthetic macrocycle-based supramolecular systems
This review article covers the design and synthesis of macrocyclic compounds-based supramolecular systems and materials with aggregation-induced emission properties and broad application potentials.
Chem. Commun., 2025, Advance Article
https://doi.org/10.1039/D5CC04019A
Use of aggregation-induced emission for detection of molecular motion during solvent evaporative crystallization of α-substituted dibenzoylmethanatoboron difluoride complex
Hierarchical changes in molecular motion during evaporative crystallization were studied based on excited-state dynamics of the AIE molecule, visualizing liquid-like clusters as nucleation precursors and providing insights into polymorph formation.
Chem. Commun., 2025, Advance Article
https://doi.org/10.1039/D5CC03168K
Positional isomerism-directed formation of hydrogen-bonded organic frameworks with distinct single-crystal transformation pathways
Positional isomers drive the formation of emissive cage- and channel-type hydrogen-bonded organic frameworks with distinct single-crystal transformation behaviors.
Chem. Commun., 2025,61, 13113-13116
https://doi.org/10.1039/D5CC03678J
Regulation of the frontier molecular orbitals and photophysical properties of boron tropolonate complexes by regioselective functionalization
Regioselective functionalization of boron tropolonates, which consist of an even-electron/odd-atom π-system, results in selective control of molecular orbital energy.
Chem. Commun., 2025, Advance Article
https://doi.org/10.1039/D5CC04171F
A J-aggregating cyanine-based NIR-II optical sensor for DNA aptamer-mediated detection and imaging of quinine
A NIR-II dye-displacement assay integrating a quinine-specific aptamer with a J-aggregating cyanine dye enables sensitive, selective detection and fluorescence imaging of quinine under physiological conditions.
Chem. Commun., 2025, Advance Article
https://doi.org/10.1039/D5CC03180J
A trident-like multi-cationic photosensitizer with stabilized membrane camouflage for efficient tumor-targeted photodynamic therapy
We report a novel trident-like multi-cation photosensitizer (PS) with stabilized membrane camouflage for efficient tumor-targeted photodynamic therapy. Its rational design boosts ROS generation and overcomes PS leakage in biomimetic delivery systems.
Chem. Commun., 2025,61, 12733-12736
https://doi.org/10.1039/D5CC02248G
Balancing UV-to-blue light conversion by membrane-embedded AIE antennas for enhanced photosynthesis
Cationic tetraphenylethylene-based amphiphiles were developed as AIE-active membrane antennas for balanced ultraviolet to blue light conversion to enhance algal photosynthesis.
Chem. Commun., 2025,61, 12313-12316
https://doi.org/10.1039/D5CC03540F
Planar chiral orange-red TADF materials with AIE properties for efficient circularly polarized OLEDs
Two orange-red planar chiral thermally activated delayed fluorescence emitters exhibit aggregation-induced emission. Their organic light-emitting diodes and circularly polarized devices show low efficiency roll-offs and high dissymmetry factors.
Chem. Commun., 2025,61, 11766-11769
https://doi.org/10.1039/D5CC02694F
Triptycene-fused multi-resonance TADF material endows high-efficiency electroluminescence and low efficiency roll-off
The triptycene-fused MR-TADF emitter exhibits an EQEmax of 27.0% and low efficiency roll-off, advancing high-performance MR-TADF materials.
Chem. Commun., 2025,61, 11191-11194
https://doi.org/10.1039/D5CC03324A
Efficient supramolecular artificial light-harvesting systems based on an AIE-active calix[4]arene derivative for cross-dehydrogenative coupling reaction
A calix[4]arene-derived AIE macrocycle (named T1) acted as an energy donor in artificial light-harvesting systems (LHSs). The T1-based LHS enabled photocatalytic cross-dehydrogenative coupling reactions.
Chem. Commun., 2025,61, 9654-9657
https://doi.org/10.1039/D5CC01914A
Multichannel afterglow regulated by protonation-induced reversed intersystem crossing
The precise regulation of ΔEST and kRISCvia protonation/deprotonation enables dynamic switching between TADF and RTP afterglow.
Chem. Commun., 2025,61, 9448-9451
https://doi.org/10.1039/D5CC01443C
Interpretable prediction of aggregation-induced emission molecules based on graph neural networks
Based on interpretable graph neural networks, we have established a new efficient workflow for developing AIE materials.
Chem. Commun., 2025,61, 8899-8902
https://doi.org/10.1039/D5CC01949D
High-contrast tricolored mechanofluorochromism of a novel gold(I)-based AIEgen achieved through the phosphino-type auxiliary ligand modulation strategy
A gold(I) complex with a phosphino-type ligand can simultaneously show AIE and high-contrast tricolored mechanofluorochromism for the first time, and its application in inkless writing information storage is developed.
Chem. Commun., 2025,61, 8504-8507
https://doi.org/10.1039/D5CC01801C
About this collection
Aggregation-induced emission , a concept coined by Professor Ben Zhong Tang at the beginning of this century, refers to a unique phenomenon that a luminogen is weakly emissive in a dilute solution as a molecular species but luminesces intensely upon aggregate formation. Over the last quarter-century, AIE has attracted much research interest and has developed into an active branch of scientific research. The first paper to use the AIE terminology was published in Chem. Commun., 2001, 1740-1741, which has been cited almost 7,000 times, becoming one of the most cited articles in the journal’s history. 2026 marks the 25th anniversary of the AIE conceptualization. To celebrate the anniversary, we’re delighted to showcase this themed collection on AIE research, Guest Edited by Ben Zhong Tang (Chinese University of Hong Kong, China), Bin Liu (National University of Singapore, Singapore), Kazuo Tanaka (Kyoto University, Japan), Martin Bryce (Durham University, UK) and Anjun Qin (South China University of Technology, China).