This review aims to collect advancements in enantioselective palladium-catalyzed cyclization reactions over the past eleven years, and it is organized into thirteen sections depending on the different types of transformations involved.
Developments in synthetic methods for and reactivity of heavier tetrylene and tetrylyne complexes of the d-block elements are summarised, with a view towards cooperative bond activation and utilisation in catalysis.
This review analyses recent advances and strategies employed in the Pd-AAA of nucleophilic prochiral heterocycles. Each section is focused on a specific heterocycle, where optimisation data and reaction scope have been carefully analysed.
The review summarizes the increasing applications of the chiral bisphosphine ligand Ph-BPE in catalytic asymmetric reactions in the past twenty years.
The asymmetric catalytic synthesis of 1,2-diamines has received considerable interest, due to their presence in biologically active compounds and their applications for the development of synthetic building blocks, chiral ligands and organocatalysts.