Evaluating Np(v) disproportionation: effect of Np concentration

Sara E. Gilson, Megan E. Simms, Frankie D. White, Laetitia H. Delmau and Luke R. Sadergaski

RSC Adv., 2026, 16, 16040
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Thermal decomposition of neptunyl ammonium nitrate: mechanistic insights and structural characterization of the Np2O5 intermediate phase

Kathryn M. Lawson, Tyler L. Spano, Jordan M. Roach, Connor J. Parker, Sara B. Isbill and Andrew Miskowiec

Inorg. Chem. Front., 2025, 12, 5915
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Effect of hydration of a room temperature ionic liquid on the cation–cation interaction of UO22+ and NpO2+ ions

Parveen Kumar Verma, Arunasis Bhattacharyya and Prasanta Kumar Mohapatra

New J. Chem., 2023, 47, 7391
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Probing the protonation and reduction of heptavalent neptunium with computational guidance

Grant C. Benthin, Harindu Rajapaksha, Emma L. Markun, Sara E. Mason and Tori Z. Forbes

Dalton Trans., 2024, 53, 16170
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The crystal orientation of THF clathrates in nano-confinement by in situ polarized Raman spectroscopy

Mrityunjay K. Sharma, Xin Ning Leong, Carolyn A. Koh and Ryan L. Hartman

Lab Chip, 2024, 24, 798
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Electroanalytical characterization of Np(vi)/Np(v) redox in a pentadentate ligand environment and stabilization of [NpVO2]+ by hydrogen bonding

Emily R. Mikeska, T. Davis Curry, Richard E. Wilson and James D. Blakemore

Dalton Trans., 2024, 53, 19126
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Crystallization of a Neptunyl Oxalate Hydrate from Solutions Containing NpV and the Uranyl Peroxide Nanocluster U60Ox30

Kyson R. Smith, Jan Ilavsky and Amy E. Hixon

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202203814

Improving understanding of NpO2 and Np2O5 through vibrational spectroscopy

Sara E. Gilson, Luke R. Sadergaski and Adam J. Parkison

Journal of Solid State Chemistry, 2024, 339, 124954
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Density Functional Theory Guided Investigation of Ligand‐Induced Neptunyl‐Neptunyl Interactions

Logan J. Augustine, Mikaela Mary F. Pyrch, Dmytro V. Kravchuk, Jay M. Williams, Sara E. Mason and Tori Z. Forbes

Eur J Inorg Chem, 2023, 26
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Feasibility analysis of co-depositing Ca-Si gels with microbial minerals in concrete crack solution

Benqiang Pang, Xuan Zhang, Haitao Zhao, Qiwei Zhan and Chenpeng Song

Journal of Building Engineering, 2024, 96, 110379
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Periodic Trends within Actinyl(VI) Nitrates and Their Structures, Vibrational Spectra, and Electronic Properties

Matthieu Autillo, Richard E. Wilson, Monica Vasiliu, Gabriel F. de Melo and David A. Dixon

Inorg. Chem., 2022, 61, 15607
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Applying Two-Dimensional Correlation Spectroscopy and Principal Component Analysis to Understand How Temperature Affects the Neptunium(V) Absorption Spectrum

Luke R. Sadergaski and Kyle Morgan

Chemosensors, 2022, 10, 475
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Cation–Cation Interactions in Neptunium(V,VI)-diglycolamide System

Christelle Tamain, Matthieu Autillo, Dominique Guillaumont, Luca Briscese and Claude Berthon

Inorg. Chem., 2025, 64, 13030
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Bonding and reactivity of isostructural uranyl and neptunyl peroxide phases

Harindu Rajapaksha, Grant C. Benthin, Emma L. Markun, Cameron J. Flester, Sara E. Mason and Tori Z. Forbes

Commun Chem, 2025, 8
DOI: 10.1038/s42004-025-01733-6

Dinuclear Complexes of Uranyl, Neptunyl, and Plutonyl: Structures and Oxidation States Revealed by Experiment and Theory

Tian Jian, Monica Vasiliu, Zachary R. Lee, Zhicheng Zhang, David A. Dixon and John K. Gibson

J. Phys. Chem. A, 2022, 126, 7695
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Insights into the Mechanism of Neptunium Oxidation to the Heptavalent State

Dmytro V. Kravchuk, Logan J. Augustine, Harindu Rajapaksha, Grant C. Benthin, Enrique R. Batista, Ping Yang and Tori Z. Forbes

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202304049

Three-Dimensional Noncovalent Interaction Network within [NpO2Cl4]2– Coordination Compounds: Influence on Thermochemical and Vibrational Properties

Harindu Rajapaksha, Grant C. Benthin, Dmytro V. Kravchuk, Haley Lightfoot, Sara E. Mason and Tori Z. Forbes

Inorg. Chem., 2023, 62, 17265
DOI: 10.1021/acs.inorgchem.3c02502

Periodic Density Functional Theory Calculations of Uranyl Tetrachloride Compounds Engaged in Uranyl–Cation and Uranyl–Hydrogen Interactions: Electronic Structure, Vibrational, and Thermodynamic Analyses

Logan J. Augustine, Harindu Rajapaksha, Mikaela Mary F. Pyrch, Maguire Kasperski, Tori Z. Forbes and Sara E. Mason

Inorg. Chem., 2023, 62, 372
DOI: 10.1021/acs.inorgchem.2c03476

Accessibility and Reactivity of Pentavalent Plutonium under Alkaline Conditions

Dmytro V. Kravchuk, Emily R. Mikeska and Richard E. Wilson

J. Am. Chem. Soc., 2026, 148, 6926
DOI: 10.1021/jacs.5c16525

PCET‐Driven Reactivity of Neptunyl(VI) Yields Oxo‐Bridged Np(V) and Np(IV) Species

Emily R. Mikeska, Richard E. Wilson and James D. Blakemore

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202402963