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Light‐Responsive Aldehyde‐Reduction Catalysis Through Catalyst Encapsulation
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An Adaptable Water-Soluble Molecular Boat for Selective Separation of Phenanthrene from Isomeric Anthracene
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Confinement Effects of Coordination Cages on the Synthesis and Application of Polyoxometalates
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Assembly of Six Types of Heteroleptic Pd2L4 Cages under Kinetic Control
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An Organo‐Palladium Host Built from a Dynamic Macrocyclic Ligand: Adaptive Self‐Assembly, Induced‐Fit Guest Binding, and Catalysis
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High‐Throughput Computational Evaluation of Low Symmetry Pd2L4Cages to Aid in System Design**
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Chirality‐Driven Self‐Assembly of Discrete, Homochiral FeII2L3 Cages
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Dynamic Metallosupramolecular Cages Containing 12 Adaptable Pockets for High-Order Guest Binding Beyond Biomimicry
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Shape‐Complementary Multicomponent Assembly of Low‐Symmetry Co(III)Salphen‐Based Coordination Cages
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Low‐Symmetry Macrocycles and Cages for Carbohydrate Recognition
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Fine‐Tuning of the Sequential Self‐Assembly of Entangled Polyhedra by Exploiting the Side‐Chain Effect
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Noble metal nanoparticles meet molecular cages: A tale of integration and synergy
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Design, Characterizations and Host‐Guest Properties of a New Metal‐Organic Cage Based on Half‐Sandwich Rhodium Moieties
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Triamine and Tetramine Edge-Length Matching Drives Heteroleptic Triangular and Tetragonal Prism Assembly
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Effector Regulated Catalytic Cyclization of Alkynoic Acids Using Pt2L4 Cages
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Crucial Role of the Heteroatom and Bite Angle Influencing Spin States and Dinuclear Fe(II) Helicate Formation in 1,3,4-Thia/Oxadiazole Ligand
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Beyond Platonic: How to Build Metal–Organic Polyhedra Capable of Binding Low-Symmetry, Information-Rich Molecular Cargoes
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Resorcinarene-Based Supramolecular Capsules: Supramolecular Functions and Applications
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Recent advances in the design and applications of platinum-based supramolecular architectures and macromolecules
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Ligand Isomerism in Palladium(II)‐Based Multi‐Cavity Discrete Coordination Cages
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Controlled Construction of Heteroleptic [Pd2(LA)2(LB)(LC)]4+Cages: A Facile Approach for Site‐Selective endo‐Functionalization of Supramolecular Cavities
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Incorporation of a Phosphino(pyridine) Subcomponent Enables the Formation of Cages with Homobimetallic and Heterobimetallic Vertices
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A Series of New Manganese(II) Polynuclear Complexes Based on Nitrothiacalix[4]arenes: The Study of Interplay between Macrocycle Platform Flexibility and Structural Diversity of Coordination Compounds
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A tetrahedron from homooxacalix[3]arene, the fifth Platonic polyhedron from calixarenes and uranyl
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A Lantern‐Shaped Pd(II) Cage Constructed from Four Different Low‐Symmetry Ligands with Positional and Orientational Control: An Ancillary Pairings Approach
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Multicomponent Reactions Mediated by Supramolecular Containers
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Tetramine Aspect Ratio and Flexibility Determine Framework Symmetry for Zn8L6Self‐Assembled Structures
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Nonaqueous Emulsion Polycondensation Enabled by a Self‐Assembled Cage‐like Surfactant
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Chemistry A European J, 2022, 28
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CH‐π Multi‐Interaction‐Driven Recognition and Isolation of Planar Compounds in a Spheroidal Polyaromatic Cavity
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Chemistry A European J, 2022, 28
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Computational Modeling of Supramolecular Metallo-organic Cages–Challenges and Opportunities
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Supramolecular Shish Kebabs: Higher Order Dimeric Structures from Ring‐in‐Rings Complexes with Conformational Adaptivity
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Chirality Interplay between the Interior and Exterior of Metal–Organic Cages
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Transient Metallo‐Lipidoid Assemblies Amplify Covalent Catalysis of Aqueous and Non‐Aqueous Reactions
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Solid-State Self-Assembly: Exclusive Formation and Dynamic Interconversion of Discrete Cyclic Assemblies Based on Molecular Tweezers
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Structural Flexibility in Metal-Organic Cages
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Visible‐Light‐Responsive Self‐Assembled Complexes: Improved Photoswitching Properties by Metal Ion Coordination**
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Remote optical chirality transfer via helical polyaromatic capsules upon encapsulation
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Effector Regulated Catalytic Cyclization of Alkynoic Acids Using Pt2L4 Cages
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Role of Molecular Interactions in Supramolecular Polypeptide–Polyphenol Networks for Engineering Functional Materials
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Guest Encapsulation Alters the Thermodynamic Landscape of a Coordination Host
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Nanogels with Metal‐Organic Cages as Functional Crosslinks
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Metallo‐Supramolecular Helicates as Surface‐Enhanced Raman Scattering (SERS) Substrates with High Tailorability
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Coordination driven discrete metallopolygons and cages from unsymmetric bidentate ligands
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A Family of Externally-Functionalised Coordination Cages
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Ion Mobility Mass Spectrometry for Large Synthetic Molecules: Expanding the Analytical Toolbox
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Beyond symmetric self-assembly and effective molarity: unlocking functional enzyme mimics with robust organic cages
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Flexibility‐Aided Orientational Self‐Sorting and Transformations of Bioactive Homochiral Cuboctahedron Pd12L16
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3D fractal expanding of a Sierpiński triangular-faced supramolecular cage for enhanced photocatalytic performance
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Chirality Communication and Transmission Within Palladium(II) Quadruple‐Stranded Helicates
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Chirality Interplay between the Interior and Exterior of Metal–Organic Cages
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Heterotrimetallic Double Cavity Cages: Syntheses and Selective Guest Binding
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Pseudo‐heterolepticity in Low‐Symmetry Metal‐Organic Cages
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Construction of Photo‐Responsive Pd2L4‐Type Nanocages based on Feringa's Second‐Generation Motor and Its Guest Binding Ability for C60
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Guest-Induced Reversible Transformation between an Azulene-Based Pd2L4 Lantern-Shaped Cage and a Pd4L8 Tetrahedron
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Two Zirconium Metal–Organic Cages with S4 and D2d Symmetry: Construction and Detection of Antibiotics
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Hierarchical packing of racemic metallosupramolecular cages with Ni(II)-based triple-stranded helicate building blocks
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Formkomplementäre Multikomponenten Assemblierung von Niedrigsymmetrischen Co(III)Salphen Koordinationskäfigen
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Pd(II)‐vermittelte Assemblierung einer Reihe von löslichen Diketopyrrolopyrrol‐Chromophor‐Stapeln**
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Harnessing a Pd4 Water-Soluble Molecular Capsule as a Size-Selective Catalyst for Targeted Oxidation of Alkyl Aromatics
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Theoretical Study on Rate-Determining Reactions for Constructing Self-Assembling Molecular Cages Controlled by Distorted Ditopic Ligands
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Metal–organic cycle-based multistage assemblies
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Combinatorial Self‐Assembly of Coordination Cages with Systematically Fine‐Tuned Cavities for Efficient Co‐Encapsulation and Catalysis
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Combinatorial Self‐Assembly of Coordination Cages with Systematically Fine‐Tuned Cavities for Efficient Co‐Encapsulation and Catalysis
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Self‐Assembly of an [M8L24]16+ Intertwined Cube and a Giant [M12L16]24+ Orthobicupola
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Iterative synthesis, structures, and properties of acyclic and cyclic acridone oligomers
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Endohedrally Functionalized Heteroleptic Coordination Cages for Phosphate Ester Binding
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Metallocavitins as Advanced Enzyme Mimics and Promising Chemical Catalysts
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Orientational Compatibility Modulation of Ligands in Low‐Symmetry Multi‐Cavity Discrete Coordination Cages by Neighbouring Cage Participation
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Highly Anisotropic Pd2Lab2Lcc2 and Pd2Lab2Lcd2 Type Cages by Heteromeric Completive Self‐Sorting
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Accurate Matching of a Secondary Amino-Functionality Metal–Organic Cage for Selective Recognition and Supramolecular Binding during Photoinduced Hydrogen Evolution
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Intricate Low-Symmetry Ag6L4 Capsules Formed by Anion-Templated Self-Assembly of the Stereoisomers of an Unsymmetric Ligand
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Charge‐Assisted Halogen Bonding in an Ionic Cavity of a Coordination Cage Based on a Copper(I) Iodide Cluster
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Urea‐Functionalized Fe4L6 Cages for Supramolecular Gold Catalyst Encapsulation to Control Substrate Activation Modes
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Ligand Conformation Controls Assembly of a Helicate/Mesocate, Heteroleptic [Pd2L2L′2] Cages and a Six‐Jagged [Pd6L12] Ring
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Highly Anisotropic Pd2Lab2Lcc2 and Pd2Lab2Lcd2 Type Cages by Heteromeric Completive Self‐Sorting
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An Aluminum-Based Metal–Organic Cage for Cesium Capture
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Non-statistical assembly of multicomponent [Pd2ABCD] cages
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Pseudo‐heterolepticity in Low‐Symmetry Metal‐Organic Cages
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Chiral Selectivity between Pd12Ala24 Metal–Organic Cages Containing Endohedral Chiral Ligands and Their Chiral Counterions
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Modulating the Shape of Short Metal‐Mediated Heteroleptic Tapes of Porphyrins
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Single‐Step Synthesis of a Heterometallic [Cu2PdL4]2+ Hybrid Metal–Organic Coordination Cage
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Construction and Hierarchical Self-Assembly of Multifunctional Coordination Cages with Triangular Metal–Metal-Bonded Units
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Photoswitchable coordination cages
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Solvent‐Controlled Separation of Integratively Self‐Sorted Pd2LA2LB2 Coordination Cages
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Cage Match: Comparing the Anion Binding Ability of Isostructural Versus Isofunctional Pairs of Metal‐Organic Nanocages
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Charge‐Assisted Halogen Bonding in an Ionic Cavity of a Coordination Cage Based on a Copper(I) Iodide Cluster
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Nanogels with Metal‐Organic Cages as Functional Crosslinks
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Reaktivität in Molekularen Gefäßen: Beschleunigungsmodi und Arten der Erzielbaren Selektivität
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Guest‐Facilitated Heteroleptic Assembly of Helical Anionocages Enables Reversible Chirality Modulation
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Combinatorial Coordination Self‐Assembly for Organopalladium Cages with Fine‐Tuned Structure and Function
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Solvent-Directed Social Chiral Self-Sorting in Pd2L4 Coordination Cages
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Synthesis, Structures, and Complexation with Phenolic Guests of Acridone‐Incorporated Arylene–Ethynylene Macrocyclic Compounds
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Light‐Driven Ratchet Mechanism Accelerates Regioselective Metal‐Cation Exchange in a Heterobimetallic Helicate
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Discrete Heterotrimetallic Assemblies Based on Rod‐Shaped FeII‐Metalloligands and a ZnII‐Porphyrin/RuII‐Metallacycle
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Orientational Self-Sorting in Octahedral Palladium Cages: Scope and Limitations of the “cis Rule”
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LiBF4‐Induced Rearrangement and Desymmetrization of a Palladium‐Ligand Assembly
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Discrete metallosupramolecular architectures with amino acids
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Heteroleptic Tripalladium(II) Cages
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Metal–Organic Cages: Applications in Organic Reactions
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Folding encapsulation toward Lindqvist polyoxometalates within adaptive coordination cages for catalysis
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Light‐Driven Ratchet Mechanism Accelerates Regioselective Metal‐Cation Exchange in a Heterobimetallic Helicate
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Synthesis of 177Lu-Labeled, Somatostatin-2 Receptor-Targeted Metalla-Assemblies: Challenges in the Design of Supramolecular Radiotherapeutics
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Reversible Multielectron Release from Redox-Active Three-Dimensional Molecular Barrels with Ruthenium-Alkenyl Moieties
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Probing the Importance of Host Symmetry on Carbohydrate Recognition
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Complementarity and Preorganisation in the Assembly of Heterometallic–Organic Cages via the Metalloligand Approach—Recent Advances
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3,5-bis(4-pyridyl)-1,2,4-Oxadiazole: an Unsymmetric Bidentate Ligand, Polymeric Silver Complex and Antimicrobial Activity Study
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Solvent‐Controlled Separation of Integratively Self‐Sorted Pd2LA2LB2 Coordination Cages
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Supramolecular Coordination Cages for Artificial Photosynthesis and Synthetic Photocatalysis
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Metallocavitins as Promising Industrial Catalysts: Recent Advances
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Supramolecular Eu(III)4L4 Tetrahedra-Based Films for Luminescence Sensing of Volatile Amines with Sub-ppt-Level Detection Limit
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Urea‐Functionalized Fe4L6 Cages for Supramolecular Gold Catalyst Encapsulation to Control Substrate Activation Modes
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Controlling the Assembly of PdII/Bianthryl‐Based Monomeric and Dimeric Interlocked Cages by Steric Effects
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Guest‐Facilitated Heteroleptic Assembly of Helical Anionocages Enables Reversible Chirality Modulation
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A Combined Experimental and Computational Exploration of Heteroleptic cis‐Pd2L2L’2 Coordination Cages through Geometric Complementarity
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Chemistry A European J, 2025, 31
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Self-assembled palladium(II) metallacycles bearing imidazole motifs: Synthesis, characterization, and their in vitro cytotoxicity evaluation
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Flexibility‐Aided Orientational Self‐Sorting and Transformations of Bioactive Homochiral Cuboctahedron Pd12L16
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Host Spin‐Crossover Thermodynamics Indicate Guest Fit
Jieyu Zheng, Larissa K. S. von Krbek, Tanya K. Ronson and Jonathan R. Nitschke
Angewandte Chemie, 2022, 134
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Double-Bridging Increases the Stability of Zinc(II) Metal–Organic Cages
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Self-assembly of nanostructures with high complexity based on metal⋯unsaturated-bond coordination
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Deciphering the mechanism of structural transformation between Pd3L6 and Pd4L8 metal-organic cages
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Stoichiometric Control of Guest Recognition of Self‐Assembled Palladium(II)‐Based Supramolecular Architectures
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Chemistry — An Asian Journal, 2023, 18
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Endohedral funktionalisierte heteroleptische Koordinationskäfige für die Bindung von Phosphatestern
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Angewandte Chemie, 2022, 134
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Discrimination of Perfluorinated Arenes/Alkanes by Modulable Polyaromatic Capsules
Urara Kai, Ryuki Sumida, Yuya Tanaka and Michito Yoshizawa
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Terpyridine-Based Metal–Organic Cage with Enhanced Emission via Coordination-Induced Rigidity
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Self‐Assembly of an [M8L24]16+ Intertwined Cube and a Giant [M12L16]24+ Orthobicupola
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Angew Chem Int Ed, 2024, 63
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Dye-Binding Metal–Organic Cage for Highly Efficient Multiphoton Activation of C(sp3)–H Bonds
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Virus-like Cage Hybrid: Covalent Organic Cages Attached to Metal Organic Cage
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Chemistry, 2022, 4, 865
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Diastereoselective Self‐Assembly of Low‐Symmetry PdnL2n Nanocages through Coordination‐Sphere Engineering**
Paulina Molinska, Andrew Tarzia, Louise Male, Kim E. Jelfs and James E. M. Lewis
Angewandte Chemie, 2023, 135
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Exploring the Geometric Space of Metal–Organic Polyhedrons (MOPs) of Metal-Oxo Clusters
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Inorg. Chem., 2021, 60, 14772
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Selective Supramolecular Recognition of Nitroaromatics by a Fluorescent Metal–Organic Cage Based on a Pyridine-Decorated Dibenzodiaza-Crown Macrocyclic Co(II) Complex
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Exploiting Supramolecular Interactions to Control Isomer Distributions in Reduced-Symmetry [Pd2L4]4+ Cages
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Inorg. Chem., 2023, 62, 1833
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Heterotrimetallic Double Cavity Cages: Syntheses and Selective Guest Binding
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Heteromeric Completive Self-Sorting in Coordination Cage Systems
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Self-Assembly of Two Tubular Metalloligand-Based Palladium–Organic Cages as Hosts for Polycyclic Aromatic Hydrocarbons
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Inorg. Chem., 2023, 62, 4048
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FRET-Mediated Photoswitchable Catalytic Metallacage with Tunable Activity for Organic Dye Degradation
Gui-Yuan Wu, Ling Hu, Ling Zhu, Zi-Yi Xu, Wei-Liang Hu, Lianrui Hu, Yi Qin, Xiao He, Ben Zhong Tang and Zhou Lu
Inorg. Chem., 2025, 64, 6865
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Visible‐Light‐Responsive Self‐Assembled Complexes: Improved Photoswitching Properties by Metal Ion Coordination**
Ray G. DiNardi, Anna O. Douglas, Ruoming Tian, Jason R. Price, Mohammad Tajik, William A. Donald and Jonathon E. Beves
Angewandte Chemie, 2022, 134
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Spin Crossover Induced by Changing the Identity of the Secondary Metal Ion from PdII to NiII in a Face‐Centered FeII8MII6 Cubic Cage**
Hyunsung Min, Alexander R. Craze, Matthew J. Wallis, Ryuya Tokunaga, Takahiro Taira, Yutaka Hirai, Mohan M. Bhadbhade, Daniel J. Fanna, Christopher E. Marjo, Shinya Hayami, Leonard F. Lindoy and Feng Li
Chemistry A European J, 2023, 29
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Guest Segregation in Heteromeric Multicage Systems
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Dual Capture of Iodine and Methyl Iodide Using Nonporous Nitrogen-Enriched Palladium(II) Assemblies
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Helicity induction by innocent anion in a quadruple stranded cage
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Journal of Organometallic Chemistry, 2021, 950, 121984
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Guest‐Dependent Isomer Convergence of a Permanently Fluxional Coordination Cage
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Angew Chem Int Ed, 2022, 61
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Thiacalix[4]arene macrocycles as versatile building blocks for the rational design of high-nuclearity metallic clusters, metallamacrocycles, porous coordination cages and containers
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Host Spin‐Crossover Thermodynamics Indicate Guest Fit
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Angew Chem Int Ed, 2022, 61
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Ring‐Size Control and Guest‐Induced Circularly Polarized Luminescence in Heteroleptic Pd3A3B3 and Pd4A4B4 Assemblies
Kristina E. Ebbert, Elie Benchimol, André Platzek, Christoph Drechsler, Joseph Openy, Shota Hasegawa, Julian J. Holstein and Guido H. Clever
Angewandte Chemie, 2024, 136
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High‐Throughput Computational Evaluation of Low Symmetry Pd2L4Cages to Aid in System Design**
Andrew Tarzia, James E. M. Lewis and Kim E. Jelfs
Angew Chem Int Ed, 2021, 60, 20879
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Thermo-/Mechano-Chromic Chiral Coordination Dimer: Formation of Switchable and Metastable Discrete Structure through Chiral Self-Sorting
Kazuyoshi Takimoto, Takumi Shimada, Kazuhiko Nagura, Jonathan P. Hill, Takashi Nakanishi, Hidetaka Yuge, Shinsuke Ishihara, Jan Labuta and Hisako Sato
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Beyond Microporosity in Porous Organic Molecular Materials (POMMs)
Chris Halliwell, Jesus Ferrando Soria and Antonio Fernandez
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A Lantern‐Shaped Pd(II) Cage Constructed from Four Different Low‐Symmetry Ligands with Positional and Orientational Control: An Ancillary Pairings Approach
Dan Preston and Jack D. Evans
Angewandte Chemie, 2023, 135
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The cutting edge of lantern-shaped cage methodologies
Zack T. Avery, Jess L. Algar and Dan Preston
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Post-synthetic modifications of metal–organic cages
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Developing sophisticated microenvironments in metal-organic cages
James E.M. Lewis
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Heteroleptic Triple-Stranded Metallosupramolecules with Hydrophobic Inner Voids
Thanh Nhan Nguyen, Ngoc Minh Tran, In-Hyeok Park and Hyojong Yoo
ACS Omega, 2022, 7, 13067
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Chiral Pd2L4 Capsules from Readily Accessible Tröger's Base Ligands Inducing Circular Dichroism on Fullerenes C60 and C70
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Angew Chem Int Ed, 2025, 64
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Multi‐Decker Emissive Supramolecular Architectures Based on Shape‐Complementary Ligands Pair
Jianjun Ma, Ningxu Han, Hao Yu, Jiaqi Li, Junjuan Shi, Shaozhi Wang, Houyu Zhang and Ming Wang
Small, 2022, 18
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The Story of the Little Blue Box: A Tribute to Siegfried Hünig
Xiao‐Yang Chen, Hongliang Chen and J. Fraser Stoddart
Angew Chem Int Ed, 2023, 62
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Unsymmetric Chiral Ligands for Large Metallo‐Macrocycles: Selectivity of Orientational Self‐Sorting
Ondřej Jurček, Subhasis Chattopadhyay, Elina Kalenius, Juha M. Linnanto, Anniina Kiesilä, Pia Jurček, Petr Radiměřský and Radek Marek
Angewandte Chemie, 2024, 136
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Single‐Step Synthesis of a Heterometallic [Cu2PdL4]2+ Hybrid Metal–Organic Coordination Cage
Shannon Thoonen, Samuel E. Walker, David L. Marshall, Therese M. Fulloon, Samuel Brandon, Alasdair I. McKay, Martin J. Paterson, Kathleen M. Mullen, James D. Crowley, Kellie L. Tuck and David R. Turner
Angewandte Chemie, 2025, 137
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Reactivity Inside Molecular Flasks: Acceleration Modes and Types of Selectivity Obtainable
Leonidas‐Dimitrios Syntrivanis and Konrad Tiefenbacher
Angew Chem Int Ed, 2024, 63
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Engineering Soluble Diketopyrrolopyrrole Chromophore Stacks from a Series of Pd(II)‐Based Ravels**
Irene Regeni, Rituparno Chowdhury, Kai Terlinden, Shinnosuke Horiuchi, Julian J. Holstein, Sascha Feldmann and Guido H. Clever
Angew Chem Int Ed, 2023, 62
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An Organo‐Palladium Host Built from a Dynamic Macrocyclic Ligand: Adaptive Self‐Assembly, Induced‐Fit Guest Binding, and Catalysis
Dan‐Ni Yan, Li‐Xuan Cai, Shao‐Jun Hu, Yan‐Fang Zhou, Li‐Peng Zhou and Qing‐Fu Sun
Angewandte Chemie, 2022, 134
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Controlling the Complexity and Interconversion Mechanisms in Self‐Assembled [Fe2L3]4+ Helicates and [Fe4L6]8+ Cages
Rashid G. Siddique, Kasun S. A. Arachchige, Hydar A. AL‐Fayaad, John D. Thoburn, John C. McMurtrie and Jack K. Clegg
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Non‐Templated Assembly of D5h‐Symmetric Pd5L10 Rings by Precise Ligand Angle Adjustment
Laura Neukirch, Milan D. Kulas, Julian J. Holstein and Guido H. Clever
Chemistry A European J, 2024, 30
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Anion‐Driven Programmable Chiral Self‐Sorting in Metal‐Organic Cages and Structural Transformations between Heterochiral and Homochiral Cages
Sandipan Ghorai and Ramalingam Natarajan
Chemistry A European J, 2023, 29
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Low‐Symmetry Face‐Capped Fe(II) Tetrahedra Through Anisotropic Ligand Extension
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Solvent‐Triggered Aggregation‐Induced Reversal and Enhancement of Circularly Polarized Luminescence in Chiral Salen Metalla‐Macrocycles
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Small, 2025
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Guest‐Modulated Circularly Polarized Luminescence by Ligand‐to‐Ligand Chirality Transfer in Heteroleptic PdII Coordination Cages
Kai Wu, Jacopo Tessarolo, Ananya Baksi and Guido H. Clever
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The Synthesis, Structure, and Supramolecular Chemistry of Anthracene Rings and Cages
Shinji Toyota
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Exploiting Chirality in Confined Nanospaces
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Development of Supramolecular Complexes Based on Coordination Complexes and Organic Hosts
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Metallo‐Supramolecular Helicates as Surface‐Enhanced Raman Scattering (SERS) Substrates with High Tailorability
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Orientational Compatibility Modulation of Ligands in Low‐Symmetry Multi‐Cavity Discrete Coordination Cages by Neighbouring Cage Participation
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N-Heteroatom Engineered Nonporous Amorphous Self-Assembled Coordination Cages for Capture and Storage of Iodine
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