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Abstract | Cited by

Crystal-glass phase transition in luminescent metal halides provides unique opportunities to tune the photoluminescence. Here we report four zero-dimensional Sb-based halide glasses featuring reversible phase transition upon heating and acetone triggering conditions, along with modulated luminescence properties. Benefiting from the fluorescence switching, information encryption and anti-counterfeiting applications are achieved.

Graphical abstract: Crystal-glass phase transition enabling reversible fluorescence switching in zero-dimensional antimony halides

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