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Abstract | Cited by

Herein, we report simple flow reactor designs that enable photo-controlled living radical polymerization (photo-CRP) from trithiocarbonates (TTCs) with significant enhancements in scalability and reaction rates compared to the analogous batch reactions. We also demonstrate the “on/off” photo-switchability of this reaction under flow conditions.

Graphical abstract: Improving photo-controlled living radical polymerization from trithiocarbonates through the use of continuous-flow techniques

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