Issue 14, 2009
From the journal:

Chemical Communications

Aromatic trifluoromethylation catalytic in copper†

Masahiro Oishi,a   Hideaki Kondoa  and  Hideki Amii*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Kobe University, 1-1 Rokkodai-cho, Nada-ku, Kobe, Japan
E-mail: amii@kobe-u.ac.jp
Fax: +81-78-803-5799
Tel: +81-78-803-5799

Abstract

Cu(I)-diamine complexes were found to catalyse the trifluoromethylation of aryl iodides. In the presence of a small amount of CuX (X = Cl, Br, I) and 1,10-phenanthroline (phen), the cross-coupling reactions of iodoarenes with trifluoromethylsilanes proceeded smoothly to afford trifluoromethylated aromatics in good yields.

Graphical abstract: Aromatic trifluoromethylation catalytic in copper

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B823249K
Article type
Communication
Submitted
24 Dec 2008
Accepted
30 Jan 2009
First published
23 Feb 2009

Chem. Commun., 2009, 1909-1911

Permissions

Request permissions

Aromatic trifluoromethylation catalytic in copper

M. Oishi, H. Kondo and H. Amii, Chem. Commun., 2009, 1909 DOI: 10.1039/B823249K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements