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In search of a reliable flow polymerization, group transfer polymerization (GTP) of methyl methacrylate (MMA) using gas–liquid droplet flow by argon and fully continuous flow was compared. The Đ values of polyMMA under the argon droplet flow were consistently lower than those of the fully continuous flow.

Graphical abstract: Group transfer polymerization by argon droplet flow for continuous and consistent production of well-defined polymers

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