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Abstract | Cited by

Three- vs. two-carbon N-to-N connectors give rise to monomeric, tetrahedral N2S2Co(II) (μeff = 4.24 BM) or dimeric [(N2S2)Co(II)]2 (diamagnetic) complexes, respectively. Differences in the derivative products of the Lewis acid receivers, W0(CO)3 and W0(CO)4, illustrate nucleophilicity of the thiolate sulfur lone pairs in each case, as well as their structural control.

Graphical abstract: A single carbon atom controls the geometry and reactivity of CoII(N2S2) complexes

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