ivković, Louise S. Natrajan and Marinella MazzantiChem. Commun., 2024,60, 55-58
DOI: 10.1039/D3CC05390C, Communication
The silsesquioxane ligand (iBu)7Si7O9(OH)3 (iBuPOSSH3) is revealed as an attractive system for the assembly of robust polynuclear complexes of uranium(III) and allowed the isolation of the first example of a trinuclear U(III) complex ([U3(iBuPOSS)3]) that exhibits magnetic communication and promotes dinitrogen reduction in the presence of reducing agent.