This website uses cookies to give you the best user experience. If you continue without changing your settings we'll assume you are happy to receive all RSC cookies. You can change your cookie settings by navigating to our Privacy and Cookies page and following the instructions. These instructions are also obtainable from the privacy link at the bottom of any RSC page.
Lite Version|Standard version
Home > Chemical Communications >
To gain access to this content please
Log in via your home Institution.
Log in with your member or subscriber username and password.
Download


Buy PDF Add PDF to Basket (£42.50*)
*Exclusive of taxes
This article contains 4 page(s)
Abstract | Cited by

Having identified a set of conditions that predispose a solid-state ionic compound to a pressure-induced valence transition, we investigated a series of Bi(III) perovskite oxides. We found such a transition below 10 GPa in every case, including one that we synthesised for the first time (double perovskite-type Ba2BiOsO6).

Graphical abstract: Squeezing electrons out of 6s2 lone-pairs in perovskite-type oxides

Page: ^ Top


Enter Keywords, author, title,reference, or DOI
Log in | Register