This website uses cookies to give you the best user experience. If you continue without changing your settings we'll assume you are happy to receive all RSC cookies. You can change your cookie settings by navigating to our Privacy and Cookies page and following the instructions. These instructions are also obtainable from the privacy link at the bottom of any RSC page.
Lite Version|Standard version
Home > CrystEngComm >
To gain access to this content please
Log in via your home Institution.
Log in with your member or subscriber username and password.
Download


Buy PDF Add PDF to Basket (£42.50*)
*Exclusive of taxes
This article contains 5 page(s)
Abstract | Cited by

We report the water-induced transformation of the [Zn2(dobdc)] (dobdc = 2,5-dioxidobenzene-1,4-dicarboxylate) metal–organic framework UTSA-74 to its polymorph MOF-74(Zn), contrary to a previous report on the stability of UTSA-74 under such conditions. This dissolution–recrystallization process was investigated using time-resolved in situ X-ray diffraction and kinetically analyzed using the Gualtieri crystallization model.

Graphical abstract: An in situ investigation of the water-induced phase transformation of UTSA-74 to MOF-74(Zn)

Page: ^ Top


Enter Keywords, author, title,reference, or DOI
Log in | Register